PALLADIUM-CATALYZED OXIDATIVE CARBONYLATION OF ETHYLENE AND PROPYLENE BY BUTYL NITRITE AND CARBON-MONOXIDE

被引：31

作者：

BRECHOT, P ^{[1
]}

CHAUVIN, Y ^{[1
]}

COMMEREUC, D ^{[1
]}

SAUSSINE, L ^{[1
]}

机构：

[1] INST FRANCAIS PETR,BP 311,F-92506 RUEIL MALMAISON,FRANCE

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 01期

关键词：

D O I：

10.1021/om00115a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the oxidative carbonylation of ethylene by carbon monoxide and butyl nitrite catalyzed by PdCl2- (PhCN)2 in the presence of triphenylphosphine, the pentacoordinated tetravalent palladium complex PdCl2(COOBu)NO(PPh3) has been isolated and has proved to be an intermediate in the catalytic cycle. © 1990, American Chemical Society. All rights reserved.

引用

页码：26 / 30

页数：5

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