ELECTROCHEMICAL POLYMERIZATION OF 4-METHYL-4'-VINYL-2,2'-BIPYRIDINE-CONTAINING METAL-COMPLEXES - POLYMER STRUCTURE AND MECHANISM OF FORMATION

被引：37

作者：

ELLIOTT, CM ^{[1
]}

BALDY, CJ ^{[1
]}

NUWAYSIR, LM ^{[1
]}

WILKINS, CL ^{[1
]}

机构：

[1] UNIV CALIF RIVERSIDE,RIVERSIDE,CA 92521

来源：

INORGANIC CHEMISTRY | 1990年 / 29卷 / 03期

关键词：

D O I：

10.1021/ic00328a009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The polymer structure and mechanism of formation of electroreductively polymerized 4-methyl-4′-vinyl-2,2′-bipyridine-containing metal complexes are described. Results from TLC and laser desorption Fourier transform mass spectrometry demonstrate that normal “polyvinyl-type” chains are formed through chain propagation. For electrochemically polymerized poly-Fe(vbpy)32+an average chain length of seven repeat monomer units is determined. Separate copolymerization studies of mono- and tris(vinyl)-substituted complexes provide additional information on the nature of the polymerization process. © 1990, American Chemical Society. All rights reserved.

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页码：389 / 392

页数：4

相关论文

共 19 条

[1] RECTIFYING INTERFACES USING 2-LAYER FILMS OF ELECTROCHEMICALLY POLYMERIZED VINYLPYRIDINE AND VINYLBIPYRIDINE COMPLEXES OF RUTHENIUM AND IRON ON ELECTRODES [J].

ABRUNA, HD ;

DENISEVICH, P ;

UMANA, M ;

MEYER, TJ ;

MURRAY, RW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (01) :1-5

[2] PHOTOCHEMICAL GENERATION OF RU(BPY)3+ AND O2- [J].

ANDERSON, CP ;

SALMON, DJ ;

MEYER, TJ ;

YOUNG, RC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (06) :1980-1982

[3]

Balzani V., 1978, TOP CURR CHEM, P1, DOI [10.1007/BFb0048835, DOI 10.1007/BFB0048835]

[4] SYNTHETIC AND MECHANISTIC INVESTIGATIONS OF THE REDUCTIVE ELECTROCHEMICAL POLYMERIZATION OF VINYL-CONTAINING COMPLEXES OF IRON(II), RUTHENIUM(II), AND OSMIUM(II) [J].

CALVERT, JM ;

SCHMEHL, RH ;

SULLIVAN, BP ;

FACCI, JS ;

MEYER, TJ ;

MURRAY, RW .

INORGANIC CHEMISTRY, 1983, 22 (15) :2151-2162

[5] ELECTRON-TRANSFER REACTIONS OF EXCITED-STATES - DIRECT EVIDENCE FOR REDUCTION OF CHARGE-TRANSFER EXCITED-STATE OF TRIS(2,2'-BIPYRIDINE)RUTHENIUM(II) [J].

CREUTZ, C ;

SUTIN, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (20) :6384-6385

[6] ELECTROPOLYMERIZATION OF VINYLPYRIDINE AND VINYLBIPYRIDINE COMPLEXES OF IRON AND RUTHENIUM - HOMOPOLYMERS, COPOLYMERS, REACTIVE POLYMERS [J].

DENISEVICH, P ;

ABRUNA, HD ;

LEIDNER, CR ;

MEYER, TJ ;

MURRAY, RW .

INORGANIC CHEMISTRY, 1982, 21 (06) :2153-2161

[7] UNIDIRECTIONAL CURRENT FLOW AND CHARGE STATE TRAPPING AT REDOX POLYMER INTERFACES ON BILAYER ELECTRODES - PRINCIPLES, EXPERIMENTAL DEMONSTRATION, AND THEORY [J].

DENISEVICH, P ;

WILLMAN, KW ;

MURRAY, RW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (16) :4727-4737

[8] ELECTROCHEMICAL AND SPECTRAL INVESTIGATIONS OF RING-SUBSTITUTED BIPYRIDINE COMPLEXES OF RUTHENIUM [J].

ELLIOTT, CM ;

HERSHENHART, EJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (26) :7519-7526

[9] CO-ENZYME B-12 MODEL STUDIES - AN ELECTROCHEMICAL COMPARISON OF COBALOXIME AND CO[C2(DO)(DOH)PN] COMPLEXES TO CO-ENZYME B-12 [J].

ELLIOTT, CM ;

HERSHENHART, E ;

FINKE, RG ;

SMITH, BL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (18) :5558-5566

[10] PHOTOELECTROCHEMISTRY OF TRIS(BIPYRIDYL)RUTHENIUM(II) COVALENTLY ATTACHED TO NORMAL-TYPE SNO2 [J].

GHOSH, PK ;

SPIRO, TG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (17) :5543-5549