CHANGE OF REGIOSELECTIVITY IN THE REACTION OF TIN ENOLATES AND ALPHA-BROMO KETONES - SYNTHESIS OF 1,4-DIKETONES UNDER NONRADICAL CONDITIONS

被引：25

作者：

BABA, A

YASUDA, M

YANO, K

SHIBATA, I

MATSUDA, H

机构：

[1] Department of Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1990年 / 11期

关键词：

D O I：

10.1039/p19900003205

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of tin enolates with α-halogeno ketones, strikingly effected by the addition of phosphine oxides to the reaction mixture, produced 1,4-diketones under mild conditions; the addition was shown to proceed in a non-radical manner.

引用

页码：3205 / 3207

页数：3

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