DIASTEREOFACIAL SELECTIVITY IN INTRAMOLECULAR 1,4-CONJUGATE ADDITIONS - CONCLUSIVE EVIDENCE FOR THE IMPORTANCE OF GROUND-STATE CONFORMATIONS AND THE SIGMA(ASTERISK) ORBITAL EFFECT

被引：47

作者：

GUNG, BW

FRANCIS, MB

机构：

[1] Department of Chemistry, Miami University, Oxford

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 23期

关键词：

D O I：

10.1021/jo00075a006

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The effects of the ground-state conformations and sigma* orbital energies are both important to the diastereofacial selectivity of intramolecular 1,4 conjugate additions.

引用

页码：6177 / 6179

页数：3

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