Crystal structure of (Z)-2-[(E)-2-benzylidenehydrazin-1-ylidene]-1,2-diphenylethanone

被引:4
作者
Bouchama, Abdelaziz [1 ]
Yahiaoui, Messaoud [2 ]
Chiter, Chaabane [2 ]
Setifi, Zouaoui [1 ,3 ]
Simpson, Jim [4 ]
机构
[1] Univ Ferhat Abbas Setif 1, LCIMN, Setif 19000, Algeria
[2] Univ Ferhat Abbas Setif 1, LEMMC, Setif 19000, Algeria
[3] Univ 20 Aout 1955 Skikda, Fac Technol, Dept Technol, BP 26,Route El Hadaiek, Skikda 21000, Algeria
[4] Univ Otago, Dept Chem, Dunedin, New Zealand
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词
crystal structure; Schiff base; azines; dimers; C-H center dot center dot center dot pi contacts;
D O I
10.1107/S2056989014026358
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C21H16N2O, has an almost planar (r.m.s. deviation = 0.0074 angstrom) 1,2-dibenzylidenehydrazine backbone with an approximately orthogonal almost planar (r.m.s. deviation = 0.0368 angstrom) phenylethanone substituent on one of the imine C atoms. The dihedral angle between the two mean planes is 76.99 (4)degrees. In the crystal, molecules are linked via C-H center dot center dot center dot O hydrogen bonds and C-H center dot center dot center dot pi contacts, forming a three-dimensional structure with molecules stacked along the a-axis direction.
引用
收藏
页码:35 / +
页数:8
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