CARBON PASTE-TETRATHIAFULVALENE AMPEROMETRIC ENZYME ELECTRODE FOR THE DETERMINATION OF GLUCOSE IN FLOWING SYSTEMS

被引:66
|
作者
GUNASINGHAM, H
TAN, CH
机构
[1] Department of Chemistry, National University of Singapore, Kent Ridge
关键词
Amperometric enzyme electrode; Flow injection; Glucose determination; Tetrathiafulvalene; Wall-jet electrode;
D O I
10.1039/an9901500035
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The development of a carbon paste - tetrathiafulvalene amperometric enzyme electrode for the determination of glucose in flowing streams is described. The enzyme electrode is operated in a flow-through detector based on the wall-jet configuration under flow injection (FI) and steady-state (SS) conditions. Under FI conditions, high precision (0.6%) and sample throughput (120 samples h-1) are possible. Moreover no pre-conditioning of the electrode is required. The flow system is suitable for the determination of glucose in whole blood without sample dilution. With proper orientation of the jet with respectto the enzyme electrode, high accuracy can be obtained under SS conditions.
引用
收藏
页码:35 / 39
页数:5
相关论文
共 50 条
  • [31] Voltammetric oxidation and determination of loop diuretic furosemide at a multi-walled carbon nanotubes paste electrode
    Malode, Shweta J.
    Abbar, Jyothi C.
    Shetti, Nagaraj P.
    Nandibewoor, Sharanappa T.
    ELECTROCHIMICA ACTA, 2012, 60 : 95 - 101
  • [32] An amperometric enzyme electrode and its biothel cell based on a glucose oxidase-poly(3-anilineboronic acid)-Pd nanoparticles bionanocomposite for glucose biosensing
    Sun, Lingen
    Ma, Yixuan
    Zhang, Pei
    Chao, Long
    Huang, Ting
    Xie, Qingji
    Chen, Chao
    Yao, Shouzhuo
    TALANTA, 2015, 138 : 100 - 107
  • [33] Voltammetric Determination of Ferulic Acid by Didodecyldimethylammonium Bromide/Nafion Composite Film-modified Carbon Paste Electrode
    Luo, Liqiang
    Wang, Xia
    Li, Qiuxia
    Ding, Yaping
    Jia, Jianbo
    Deng, Dongmei
    ANALYTICAL SCIENCES, 2010, 26 (08) : 907 - 911
  • [34] Sensitive and Selective Determination of Phenylhydrazine in the Presence of Hydrazine at a Ferrocene Monocarboxylic Acid Modified Carbon Nanotube Paste Electrode
    Khalilzadeh, Mohammad A.
    Karimi-Maleh, Hassan
    ANALYTICAL LETTERS, 2010, 43 (01) : 186 - 196
  • [35] Voltammetric determination of norepinephrine in the presence of acetaminophen using a novel ionic liquid/multiwall carbon nanotubes paste electrode
    Salmanpour, Sadegh
    Tavana, Toktam
    Pahlavan, Ali
    Khalilzadeh, Mohammad A.
    Ensafi, Ali A.
    Karimi-Maleh, Hassan
    Beitollahi, Hadi
    Kowsari, Elaheh
    Zareyee, Daryoush
    MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2012, 32 (07): : 1912 - 1918
  • [36] Sequential Injection Amperometric Determination of Glucose in Saliva Using a Screen-Printed Electrode Modified with a Gold-Cobalt Binary System
    Shaidarova, L. G.
    Chelnokova, I. A.
    Gafiatova, I. A.
    Gedmina, A. V.
    Budnikov, H. C.
    JOURNAL OF ANALYTICAL CHEMISTRY, 2023, 78 (03) : 372 - 377
  • [37] Application of Modified Glassy Carbon Paste Electrode for Nanomolar Determination of Adrenaline Using FFT Admittance Voltammetry in Flow Analysis
    Norouzi, Parviz
    Garakani, Tayebeh Mirzaei
    ANALYTICAL & BIOANALYTICAL ELECTROCHEMISTRY, 2009, 1 (03): : 188 - 199
  • [38] AMPEROMETRIC FLOW-INJECTION DETERMINATION OF GLUCOSE, URATE AND CHOLESTEROL IN BLOOD-SERUM BY USING SOME IMMOBILIZED ENZYME REACTORS AND A POLY(1,2-DIAMINOBENZENE)-COATED PLATINUM-ELECTRODE
    YAO, T
    SATOMURA, M
    NAKAHARA, T
    ANALYTICA CHIMICA ACTA, 1994, 296 (03) : 271 - 276
  • [39] Highly sensitive carbon paste electrode with silver-filled carbon nanotubes as a sensing element for determination of free cyanide ion in aqueous solutions
    Yari, Abdollah
    Sepahvand, Reza
    MICROCHIMICA ACTA, 2011, 174 (3-4) : 321 - 327
  • [40] DETERMINATION OF 2,4-DIMETHYLPHENOL BY ANODIC VOLTAMMETRY AND FLOW-INJECTION WITH AMPEROMETRIC DETECTION AT A GLASSY-CARBON ELECTRODE
    FERNANDEZ, C
    CHICO, E
    YANEZSEDENO, P
    PINGARRON, JM
    POLO, LM
    ANALYST, 1992, 117 (12) : 1919 - 1923