MICROBIAL OXIDATION OF 7ENDO-METHYLBICYCLO[3.2.0]HEPT-2-EN-6-ONE, 7,7-DIMETHYLBICYCLO[3.2.0]HEPT-2-EN-6-ONE AND 2EXO-BROMO-3ENDO-HYDROXY-7,7-DIMETHYLBICYCLO[3.2.0]HEPTAN-6-ONE USING ACINETOBACTER NCIMB-9871

被引：31

作者：

CARNELL, AJ ^{[1
]}

ROBERTS, SM ^{[1
]}

SIK, V ^{[1
]}

WILLETTS, AJ ^{[1
]}

机构：

[1] UNIV EXETER,DEPT BIOL SCI,EXETER EX4 4QD,DEVON,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 10期

关键词：

D O I：

10.1039/p19910002385

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A bio-Baeyer-Villiger reaction using Acinetobacter NCIMB 9871 and the bicycloheptanone 2 provided the corresponding substituted oxabicyclooctanones 6 and 7. Similarly the ketones 3 and 9 furnished the lactones 8 and 10 respectively: the lactones 6, 7 and 10 were obtained in states of high optical purity.

引用

页码：2385 / 2389

页数：5

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