DIMERIZATION OF THIOPHENE TO GIVE A LINEAR S(CH)8S FRAGMENT WITH [(C5ME5)RH(C2H4)2]

被引：67

作者：

CHIN, RM ^{[1
]}

JONES, WD ^{[1
]}

机构：

[1] UNIV ROCHESTER,DEPT CHEM,ROCHESTER,NY 14627

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 03期

关键词：

D O I：

10.1002/anie.199203571

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cleavage of a C-S bond and formation of a C-C bond are the crucial reaction steps in the construction of the S(CH)8S bridging ligand in the binuclear complex 1, which is accessible from [(C5Me5)Rh(C2H4)2] and thiophene in refluxing benzene. Compound 1 is not only interesting for its mechanistic and structural aspects, but also in connection with the catalytic hydrosulfuration of fossil fuels.

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页码：357 / 358

页数：2

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