STUDIES ON THE PRODUCTION AND DISSOCIATION OF COENZYME-B12 MODELS BY ELECTROCHEMISTRY AND SPECTROELECTROCHEMISTRY .1.

被引：0

作者：

ZHENG, GD

SUN, HR

GAO, D

CAO, XZ

机构：

来源：

ACTA CHIMICA SINICA | 1992年 / 50卷 / 10期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of CoTPP with PhCH2Cl is studied by electrochemistry and spectroelectrochemistry. The results show that the essential condition for forming the sigma cobalt-carbon bond-containing models is the central cobalt in cobalt-porphyrin reduced to lower valence (such as + 1). The relation between the formation and dissociation of cobalt-carbon bond and electric potential is discussed in detail and the mechanism of reaction of CoTPP with PhCH2Cl is also descried.

引用

页码：937 / 942

页数：6

共 12 条

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