NEW ORGANOMETAL PLATINUM-INDIUM AND COBALT-GALLIUM COMPLEXES

被引：21

作者：

FISCHER, RA

BEHM, J

机构：

[1] Anorganisch-chemisches Institut der Technischen Universität München, W-8046 Garching

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 413卷 / 1-3期

关键词：

D O I：

10.1016/0022-328X(91)80072-R

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oxidative addition of one indium-carbon bond of InR3 (R = CH2Si(CH3)3 to the highly reactive, coordinatively unsaturated platinum fragment [Cy2P(CH2CH2)PCy2]Pt (Cy = cyclo-C6H11) gives the novel platinum-indium complex [Cy2P(CH2CH2)PCy2]PCy2]Pt(InR2)(R) (3) in high yield. A single-crystal X-ray diffraction study reveals a Pt-In bond distance of 260.12(2) pm. Salt elimination between Na[Co(CO)4] and bis(neopentyl)gallium chloride constitutes a surprisingly facile access to the novel halide-free, volatile cobalt-gallium complexes of type (CO)4Co-GaR2(thf) (4; R = CH2C(CH3)3).

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页码：C10 / C14

页数：5

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