THE STANDARD ADSORPTION GIBBS ENERGY FROM SEVERAL ADSORPTION-ISOTHERMS

被引：13

作者：

TORRENT, J ^{[1
]}

SANZ, F ^{[1
]}

机构：

[1] UNIV BARCELONA,FAC QUIM,DEPT QUIM FIS,AV DIAGONAL 647,E-08028 BARCELONA,SPAIN

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1990年 / 286卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(90)85073-E

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

On the basis of a common choice of standard state for the more useful adsorption isotherms, expressions for the chemical potentials at the interphase and for the adsorption isotherm are deduced. The values of ΔGads° reported for a given system from different isotherms are then reconsidered and analyzed and the results commented upon. © 1990.

引用

页码：207 / 215

页数：9

共 16 条

[1] ADSORPTION OF ALIPHATIC MONOETHERS OF ETHYLENE-GLYCOL (ALKOXYETHANOL) AT THE FREE-WATER SURFACE AND AT THE HG/SOLUTION INTERFACE [J].

DAGHETTI, A ;

TRASATTI, S ;

ZAGORSKA, I ;

KOCZOROWSKI, Z .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1986, 204 (1-2) :299-313

[2] OPERATIONAL COMPARISON OF VARIOUS THERMODYNAMIC TREATMENTS OF ORGANIC-SUBSTANCE ADSORPTION AT THE ELECTRODE/SOLUTION INTERFACE [J].

DAGHETTI, A ;

GATTI, C ;

TRASATTI, S .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1985, 196 (01) :179-197

[3]

DAMASKIN BB, 1962, DOKL AKAD NAUK SSSR+, V147, P135

[4]

DAMASKIN BB, 1972, ADSORPTION ORGANIC C, P86

[5] STANDARD STATES AND THE FRUMKIN ADSORPTION-ISOTHERM FOR SUBSTANCES AT ELECTRODE INTERPHASES [J].

GONZALEZ, R ;

TORRENT, J ;

SANZ, F .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 244 (1-2) :53-59

[6]

GONZALEZ R, 1989, ELECTROCHIM ACTA, V34, P1883

[7]

LORENZ W, 1956, Z ELEKTROCHEM, V60, P507

[8]

MACKOR EL, 1951, RECL TRAV CHIM PAY B, V70, P747

[9] ADSORPTION OF THIOUREA AT THE POLYCRYSTALLINE SILVER ELECTRODE FROM AQUEOUS KF SOLUTIONS .2. [J].

MILKOWSKA, M .

ELECTROCHIMICA ACTA, 1988, 33 (01) :161-163

[10]

MOHILNER DM, 1966, ELECTROANALYTICAL CH, V1, P368

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