TEMPERATURE AND PRESSURE-DEPENDENCE STUDIES OF THE MOTIONS OF THE +NH3 RADICAL TRAPPED IN GAMMA-IRRADIATED AMMONIUM-PERCHLORATE SINGLE-CRYSTAL

被引：5

作者：

MICHAUT, JP ^{[1
]}

RONCIN, J ^{[1
]}

SIENKIEWICZ, A ^{[1
]}

机构：

[1] POLISH ACAD SCI,INST PHYS,WARSAW 42,POLAND

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1979年 / 53卷 / 3-4期

关键词：

D O I：

10.1080/00268947908084001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The temperature and pressure dependences of the ** plus NH//3 coupling tensors have been investigated by ESR spectroscopy. The linear variation of the reduced correlation time of the ″rotational diffusion″ motion with the reciprocal of the temperature is shown to be unrelated to the dilatation of the matrix. Comparison with ** plus ND//3 results gives the contribution to the nitrogen isotropic coupling constant of the out of plane vibration of the nitrogen atom.

引用

页码：281 / 289

页数：9

共 13 条

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