PHOTOREARRANGEMENTS OF SOME N-METHYL DIAZOLES

被引：52
作者：
BEAK, P
MESSER, W
机构：
[1] Department of Chemistry and Chemical Engineering, University of Illinois
来源：
TETRAHEDRON | 1969年 / 25卷 / 16期
关键词：
D O I：
10.1016/S0040-4020(01)82860-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The photointerconversion of 1,4-dimethylimidazole and 1,2-dimethylimidazole and the photorearrangements of 1,4,5-trimethylimidazole to 1,2,5-trimethylimidazole and of 1,3,5-trimethylpyrazole to 1,2,4- and 1,2,5-trimethylimidazole are reported. The pathway proposed for the formal interchange of the 2 and 4 positions is supported by the positionally specific photorearrangement of 1.4-dimethylimidazole-2d. © 1969.
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页码：3287 / &
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