POLYMER BATTERY EMPLOYING POLYACENIC SEMICONDUCTOR

被引：48

作者：

YATA, S

HATO, Y

SAKURAI, K

OSAKI, T

TANAKA, K

YAMABE, T

机构：

[1] KYOTO UNIV,FAC ENGN,DEPT HYDROCARBON CHEM,SAKYO KU,KYOTO 606,JAPAN

[2] KYOTO UNIV,FAC ENGN,DIV MOLEC ENGN,SAKYO KU,KYOTO 606,JAPAN

来源：

SYNTHETIC METALS | 1987年 / 18卷 / 1-3期

关键词：

ELECTRIC BATTERIES; SECONDARY - POLYACENES - Conductive - POLYMERS - Pyrolysis - SEMICONDUCTING POLYMERS;

D O I：

10.1016/0379-6779(87)90954-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Recently, we prepared a new type of polyacenic semiconductor (PAS) which is made in the form of sheet or plate with a bulk density of about 0. 4g/cm**3 from phenol-formaldehyde resin through pyrolytic process. A typical PAS has a H/C molar ratio of 0. 25 and an electrical conductivity of 10** minus **5S/cm. The specific surface area is above 2000m**2/g and the bending strength is 100-150kg/cm**2. We constructed two types of storage batteries using a disk formed PAS as electrode and solution of 1M LiClO//4 as electrolyte. These batteries displayed excellent reversibility for electrochemical doping-undoping process and very small self-discharge. We believe PAS battery is one of the first applications of conductive polymers for practical use.

引用

页码：645 / 648

页数：4