mu-Oxalato-kappa O-4(1),O-2:O-1',O-2'-bis [aqua(2,2'-bipyridine-kappa N)(nitrato-kappa O-2,O')lead(II)]

被引:1
作者
Pan, Gang-Hong [1 ]
Tang, Jin-Niu [1 ]
Huang, Zhong-Jing [1 ]
Li, Long [1 ]
Zhang, Chun-Mei [1 ]
机构
[1] Guangxi Univ Natl, Coll Chem & Chem Engn, Nanning 530006, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词
D O I
10.1107/S1600536812040196
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Pb-2(C2O4)(NO3)(2)(C10H8N2)(2)(H2O)(2)], was synthesized hydrothermally. The binuclear complex molecule is centrosymmetric, the inversion centre being located at the mid-point of the oxalate C-C bond. The PbII ion is heptacoordinated by the O atom of one water molecule, two oxalate O atoms, two nitrate O atoms and two 2,2'-bipyridine N atoms, forming an irregular coordination environemnt. Intermolecular O-H center dot center dot center dot O hydrogen bonds between water molecules and oxalate and nitrate ions result in the formation of layers parallel to (010). pi-pi interactions between pyridine rings in adjacent layers, with centroidcentroid distances of 3.584 ( 2) angstrom, stabilize the structural setup.
引用
收藏
页码:M1310 / +
页数:7
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