ENTHALPIES OF TRANSFER OF SODIUM AND POTASSIUM-CHLORIDES FROM WATER TO AQUEOUS 1,4-DIOXANE MIXTURES AT 25-DEGREES-C

被引：9
作者：
FEAKINS, D [1 ]
MULLALLY, J [1 ]
WAGHORNE, WE [1 ]
机构：
[1] NATL UNIV IRELAND UNIV COLL DUBLIN,DEPT CHEM,DUBLIN 4,IRELAND
来源：
JOURNAL OF SOLUTION CHEMISTRY | 1993年 / 22卷 / 04期
关键词：
ENTHALPIES OF TRANSFERS; AQUEOUS DIOXANE MIXTURES;
D O I：
10.1007/BF00647203
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The enthalpies of transfer of potassium and sodium chlorides from water to aqueous 1,4-dioxane mixtures (up to 17 and 54 mol percent dioxane, respectively) have been measured and corrected for ion pairing. The data for the two electrolytes are remarkably similar up to 17 mol percent dioxane and decrease monotonically with increasing dioxane concentration except for a plateau at around twenty mole percent dioxane.
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页码：311 / 319
页数：9
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