DENSITIES, VISCOSITIES, REFRACTIVE-INDEXES, AND SPEEDS OF SOUND FOR METHYL ACETOACETATE PLUS ALIPHATIC-ALCOHOLS (C1-C8)

被引:226
作者
AMINABHAVI, TM
ARALAGUPPI, MI
HAROGOPPAD, SB
BALUNDGI, RH
机构
[1] Department of Chemistry, Karnatak University
关键词
D O I
10.1021/je00009a008
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities, viscosities, refractive indices, and speeds of sound have been measured at 298.15, 303.15, and 308.15 K for the binary mixtures of methyl acetoacetate with methyl alcohol, ethyl alcohol, 1-propanol, 2-propanol, 2-methyl-1-propanol, 1-butanol, 1-pentanol, 1-hexanol, 1-heptanol, and 2-octanol. From these results, excess molar volumes, excess molar refractions, viscosity deviations, and isentropic compressibility deviations have been calculated. These results are further fitted to the polynomial relation to estimate the coefficients and standard errors. The experimental and calculated quantities are used to discuss the mixing behavior of the components.
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页码:31 / 39
页数:9
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