URANYL LUMINESCENCE DECAY IN PHOSPHORIC-ACID SOLUTION

被引:7
作者
ZHOU, P
WANG, ZL
XU, YZ
ZHANG, L
WANG, YB
机构
[1] Laser Chemistry Laboratory, Nuclear Science Department, Fudan University, Shanghai
来源
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-LETTERS | 1993年 / 175卷 / 02期
关键词
D O I
10.1007/BF02164108
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Uranyl luminescences in phosphoric acid system has been studied. Uranyl excited by a nitrogen laser shows single or biexponential luminescence decays in the phosphoric acid system. When the uranyl ion or phosphoric acid concentration are lower, a single exponential luminescence decay appears, whereas at higher uranyl ion or phosphoric acid concentrations, biexponential decay is observed. Time-resolved spectra of uranyl in this system are measured. The reasons of the phenomena are tentatively established.
引用
收藏
页码:81 / 94
页数:14
相关论文
共 20 条
[1]  
Cheng Chike, 1981, He Huaxue Yu Fangshe Huaxue, V3, P27
[2]  
CHENG CK, 1986, HUAXUE XUEBAO, V44, P900
[3]   STUDY OF LUMINESCENT FORMS OF THE URANYL-ION [J].
DARMANYAN, AP ;
KHUDYAKOV, IV .
PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1990, 52 (02) :293-298
[4]  
DESCHANX M, 1979, CHEM PHYS LETT, V63, P286
[5]  
EKSTROM, 1972, J INORG NUCL CHEM, V34, P3
[6]  
FORMOSINH SJ, 1985, J CHEM SOC F1, V81, P49
[7]   PHOTOPHYSICS OF THE EXCITED URANYL-ION IN AQUEOUS-SOLUTIONS .1. REVERSIBLE CROSSING [J].
FORMOSINHO, SJ ;
MIGUEL, MDM ;
BURROWS, HD .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1984, 80 :1717-1733
[8]  
FORMOSINHO SJ, 1984, J CHEM SOC F1, V80, P1735
[9]  
GRENTHE J, 1962, ACTA CHEM SCAND, V16, P2300
[10]  
KARMINSKI R, 1981, ANAL CHEM, V153, P1093