THE 1ST STRUCTURALLY CHARACTERIZED EARLY MAIN-GROUP METAL DIAZAALLYL COMPLEX - SYNTHESIS AND CRYSTAL-STRUCTURE OF LICPH(NPH)2.NME[(CH2)2NME2]2

被引：25

作者：

CRAGGHINE, I ^{[1
]}

DAVIDSON, MG ^{[1
]}

MAIR, FS ^{[1
]}

RAITHBY, PR ^{[1
]}

SNAITH, R ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 15期

关键词：

D O I：

10.1039/dt9930002423

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

n-Butyllithium reacts with a solution of PhNC(Ph)NHPh (N,N'-diphenylbenzamidine) and NMe[(CH2)2NMe2]2 (pmdeta) to give the complex LiCPh(NPh)2.pmdeta, which is monomeric in the solid state with a five-co-ordinate lithium cation bound to a tridentate pmdeta ligand and a bidentate amidinide anion (diazaallyl system, chelating), in which the two N-C bond lengths of 1.336(4) and 1.335(4) angstrom suggest almost uniform delocalisation along the N-C-N unit.

引用

页码：2423 / 2424

页数：2

共 50 条

[1] THE 1ST STRUCTURALLY CHARACTERIZED SODIUM PRIMARY AMIDE COMPLEX - SYNTHESIS AND CRYSTAL-STRUCTURE OF 2-PHOC6H4NHNA.NME[(CH2)2NME2]2
CRAGGHINE, I
DAVIDSON, MG
EDWARDS, AJ
RAITHBY, PR
SNAITH, R
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (19): : 2901 - 2902
[2] SYNTHESIS AND CRYSTAL-STRUCTURE OF W2[OC(CF3)2NME2]2(NME2)4
ROESKY, HW
BERTEL, N
EDELMANN, F
HERBST, R
EGERT, E
SHELDRICK, GM
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1986, 41 (12): : 1506 - 1508
[3] STRUCTURAL STUDIES OF SOME GROUP-12 METAL ALKYL ADDUCTS - THE X-RAY CRYSTAL-STRUCTURES OF ME2ZN[ME2N(CH2)2NME2], ME2CD[ME2N(CH2)2NME2], (ME3CCH2)2ZN[ME2N(CH2)2NME2] AND (ME3CCH2)2CD[ME2N(CH2)2NME2]
OBRIEN, P
HURSTHOUSE, MB
MOTEVALLI, M
WALSH, JR
JONES, AC
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 449 (1-2) : 1 - 8
[4] THE CRYSTAL-STRUCTURE OF [(PMDETA)LI(MU-CL)LI(PMDETA)][LI(C(SIME3)3)2] [PMDETA = ME2N(CH2)2NME(CH2)2NME2] - A NOVEL LINEAR CHLORINE-CENTERD CATION
BUTTRUS, NH
EABORN, C
HITCHCOCK, PB
SMITH, JD
STAMPER, JG
SULLIVAN, AC
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (12) : 969 - 970
[5] THERMALLY STABLE ARYLPALLADIUM DIAMINE COMPLEXES AS VERSATILE PRECURSORS IN ORGANOPALLADIUM CHEMISTRY - SYNTHESIS AND X-RAY MOLECULAR-STRUCTURE OF PDIPH(ME2N(CH2)2NME2) AND ITS CONVERSION TO PDMEPH(ME2N(CH2)2NME2)
DEGRAAF, W
VANWEGEN, J
BOERSMA, J
SPEK, AL
VANKOTEN, G
RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY, 1989, 108 (7-8): : 275 - 277
[6] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF THE BIS(IMINO) CYCLODIPHOSPHAZANE, [(PHN)P(NME2)(NPH)]2
KUMARAVEL, SS
KRISHNAMURTHY, SS
CAMERON, TS
LINDEN, A
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (03): : 1119 - 1121
[7] SQUARE PYRAMIDAL, ORGANO-INDIUM COMPLEXES - PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF MEIN ([MEN(CH2)2NME]ME2IN[MEN(CH2)2NME]ME2IN) AND MEIN[MENC(CH)4N]2
ARIF, AM
BRADLEY, DC
FRIGO, DM
HURSTHOUSE, MB
HUSSAIN, B
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (12) : 783 - 784
[8] Synthesis, structure, and reactivity of (η5:η1-C5Me4(CH2)2NMe2)Re(CO)2. Electron transfer behavior of a nitrosyl derivative
Godoy, Fernando
Gomez, Alejandra
Segura, Rodrigo
Doctorovich, Fabio
Pellegrino, Juan
Gaviglio, Carina
Guerrero, Paulina
Hugo Klahn, A.
Fuentealba, Mauricio
Teresa Garland, Maria
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2014, 765 : 8 - 16
[9] SYNTHESIS OF [LI(CH2SIME3) (PMDETA)] AND THE CRYSTALLINE MONOMERIC BULKY ALKYL-LITHIUM COMPLEXES [LIR(TMEDA)] AND [LIR(PMDETA)] [R = CH(SIME3)2] - X-RAY CRYSTAL-STRUCTURE OF [LI(CH(SIME3)2)(PMDETA)] (TMEDA = ME2NCH2CH2NME2, PMDETA = ME2N[CH2]2N(ME)[CH2]2NME2)
LAPPERT, MF
ENGELHARDT, LM
RASTON, CL
WHITE, AH
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (22) : 1323 - 1324
[10] Structure and reactivity of the cationic nickel compound [(η3:η1-Ind(CH2)2NMe2)Ni(PPh3)][BPh4]
Groux, LF
Zargarian, D
ORGANOMETALLICS, 2001, 20 (17) : 3811 - 3817

← 1 2 3 4 5 →