VINYL POLYMERIZATION .375. RADICAL POLYMERIZATION OF VINYL MONOMER IN WATER INITIATED WITH TIN MERCAPTIDES AND IRON(III) ION

被引：4

作者：

NAKAMURA, Y ^{[1
]}

OUCHI, T ^{[1
]}

IMOTO, M ^{[1
]}

机构：

[1] KANSAI UNIV, FAC ENGN, DEPT APPL CHEM, SUITA, OSAKA 564, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1978年 / 51卷 / 12期

关键词：

MONOMERS;

D O I：

10.1246/bcsj.51.3574

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The polymerization of the vinyl monomer was carried out in water, using either dimethylbis (ethylthio) tin or triethyl (p-tolylthio) tin as an initiator. The polymerization required the coexistence of the iron (III) ion. The initiating species was concluded to be a thiyl radical. Macromolecular tin mercaptide was much more effective than monomeric tin mercaptide.

引用

页码：3574 / 3578

页数：5

共 16 条

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