THERMAL AND NEUTRON IRRADIATION EFFECTS ON RATE OF RACEMIZATION OF D-K3CR(C2O4)3.2H2O IN SOLID STATE

被引：14

作者：

CHOWDHUR.DM

HARRIS, GM

机构：

[1] Department of Chemistry, State University of New York at Buffalo, Buffalo

[2] University Microfilms, Ann Arbor, MI

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 10期

关键词：

D O I：

10.1021/j100844a036

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The compound d-K3Cr(C2O4)3·2H2O undergoes thermal racemization in the solid state at temperatures exceeding 200°, even when previously completely dehydrated at a lower temperature. However, the presence of water vapor greatly accelerates the process, as is to be expected, since studies of the racemization of this complex in solution indicate that water may very efficiently displace at least one end of chelated oxalate. Preirradiation of the optically active crystals by pile-generated neutrons causes inhibition of the racemization reaction perhaps as a result of some sort of defect annealing process or of lattice blockage by nuclear recoil debris.

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页码：3366 / &

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