Bis[2-(1,3-benzothiazol-2-yl)phenyl-kappa C-2(1),N][1,3-bis(4-bromophenyl)-propane-1,3-dionato-kappa O-2,O ']iridium(III)

被引：1

作者：

Kim, Young -Inn ^{[1
,2
]}

Yun, Seong-Jae ^{[1
,2
]}

Kang, Sung Kwon ^{[3
]}

机构：

[1] Pusan Natl Univ, Dept Chem, Busan 609735, South Korea

[2] Pusan Natl Univ, Interdisciplinary Program Adv Informat & Display, Busan 609735, South Korea

[3] Chungnam Natl Univ, Dept Chem, Daejeon 305764, South Korea

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷

关键词：

data-to-parameter ratio = 18.0; meanω(C - C) = 0.006 A °; Rfactor = 0.030; single-crystal X-ray study; T = 203 K; wRfactor = 0.076;

D O I：

10.1107/S1600536813018394

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title complex, [Ir(C15H9Br2O2)(C13H8NS)2], lies about a crystallographic twofold rotation axis passing through the Ir-III atom and the central C atom of the bis(bromophenyl)-propane-1,3-dionate ligand. The Ir-III atom adopts a distorted octahedral geometry coordinated by two N atoms in the axial positions, and two C and two O atoms in the equatorial plane. The dihedral angle between the two thiazole ring systems in the complex is 77.45 (10)degrees.

引用

页码：M443 / +

页数：7

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