COMPLEXES OF 1,6-BIS(BENZIMIDAZOL-2-YL)-2,5-DITHIAHEXANE (BBDH) WITH ZINC(II), CADMIUM(II) AND MERCURY(II) HALIDES - CRYSTAL-STRUCTURE OF [HG(BBDH)CL2].C2H5OH

被引：11
作者：
CARBALLO, R
CASTINEIRAS, A
CONDE, MCG
HILLER, W
机构：
[1] UNIV SANTIAGO DE COMPOSTELA,DEPT QUIM INORGAN,E-15706 SANTIAGO,SPAIN
[2] TECH UNIV MUNICH,INST ANORGAN CHEM,W-8046 GARCHING,GERMANY
来源：
POLYHEDRON | 1993年 / 12卷 / 13期
关键词：
D O I：
10.1016/S0277-5387(00)87076-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We describe the synthesis and characterization by elemental analysis, conductance measurements and H-1 NMR and IR spectrometry of compounds with the general formula [M(BBDH)X2] [M = Zn, Cd or Hg; X = Cl, Br or I; BBDH = 1,6-bis(benzimidazol-2-yl)-2,5-dithiahexane], which were prepared by reaction of zinc, cadmium or mercury dihalides with BBDH in ethyl alcohol. In addition, the structure of Hg(BBDH)Cl2.EtOH (VI) was determined by single-crystal structure analysis. The mercury atom is coordinated with slightly distorted tetrahedral geometry to the unprotonated nitrogen atoms of the BBDH benzimidazolyl groups [Hg-N = 225.8(5) and 223.6(6) pm] and to two chlorine atoms [Hg-Cl = 251.3(3) ana 249.9(2) pm].
引用
收藏
页码：1655 / 1660
页数：6
相关论文
共 40 条
[1]   SYNTHESIS OF SOME IMIDAZOLE-DERIVED AND PYRAZOLE-DERIVED CHELATING-AGENTS [J].
ADDISON, AW ;
BURKE, PJ .
JOURNAL OF HETEROCYCLIC CHEMISTRY, 1981, 18 (04) :803-805
[2]   N,N-DIMETHYLBENZENOCARBOTHIOAMIDE COMPLEXES OF IIB METAL-HALIDES [J].
ARQUERO, A ;
MASAGUER, JR ;
CASTINEIRAS, A .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1985, 531 (12) :183-187
[3]   SYNTHESIS AND CHARACTERIZATION OF COPPER(II) COMPLEXES OF 1,5-BIS(QUINOLINE-8'-YL)-1,5-DITHIAPENTANE - CRYSTAL AND MOLECULAR-STRUCTURE OF [CU(BQDTP)(NO3)(OH2)](NO3) [J].
BERMEJO, E ;
CARBALLO, R ;
CASTINEIRAS, A ;
LOMBAO, A ;
HILLER, W ;
STRAHLE, J .
POLYHEDRON, 1991, 10 (13) :1579-1585
[4]   SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF COPPER(I) AND COPPER(II) COMPLEXES WITH 1,6-BIS(2-BENZIMIDAZOLYL)-2,5-DITHIAHEXANE (BBDH) - X-RAY STRUCTURE OF TRIGONAL-BIPYRAMIDAL [CU(BBDH)CL]CL.2C2H5OH [J].
BIRKER, PJMWL ;
HELDER, J ;
HENKEL, G ;
KREBS, B ;
REEDIJK, J .
INORGANIC CHEMISTRY, 1982, 21 (01) :357-363
[5]   MODEL SYSTEMS FOR TYPE-I COPPER PROTEINS - STRUCTURES OF COPPER COORDINATION-COMPOUNDS WITH THIOETHER AND AZOLE-CONTAINING LIGANDS [J].
BOUWMAN, E ;
DRIESSEN, WL ;
REEDIJK, J .
COORDINATION CHEMISTRY REVIEWS, 1990, 104 (01) :143-172
[6]   CRYSTAL AND MOLECULAR-STRUCTURES OF (1,8-BIS(2-PYRIDYL)-3,6-DITHIAOCTANE)COPPER(I) HEXAFLUOROPHOSPHATE AND PERCHLORATO(1,8-BIS(2-PYRIDYL)-3,6-DITHIAOCTANE)COPPER(II) PERCHLORATE - STEREODYNAMICS OF THE COPPER(II)-COPPER(I) COUPLE [J].
BRUBAKER, GR ;
BROWN, JN ;
YOO, MK ;
KINSEY, RA ;
KUTCHAN, TM ;
MOTTEL, EA .
INORGANIC CHEMISTRY, 1979, 18 (02) :299-302
[7]   THE REDOX PROPERTIES OF (1,6-BIS(BENZIMIDAZOL-2-YL)-2,5-DITHIAHEXANE) CHLORO-COPPER(II) CHLORIDE AS STUDIED BY CYCLIC VOLTAMMETRY [J].
CABRAL, MF ;
CABRAL, JD ;
VANRIJN, J ;
REEDIJK, J .
INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1984, 87 (01) :87-90
[8]   STRUCTURE OF 1,7-BIS(BENZIMIDAZOL-2-YL)-2,6-DITHIAHEPTANECOPPER(I) PERCHLORATE AT 233-K [J].
CARBALLO, R ;
CASTINEIRAS, A ;
HILLER, W ;
STRAHLE, J .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :1736-1738
[9]   THIONE COMPLEXES OF GROUP-IIB DIHALIDES - X-RAY CRYSTAL-STRUCTURE OF CD(ETTC)2I2 [J].
CASTINEIRAS, A ;
VIDAL, CF ;
BASTIDA, R ;
MACIAS, A ;
HILLER, W .
POLYHEDRON, 1988, 7 (24) :2503-2508
[10]   CRYSTAL AND MOLECULAR-STRUCTURE OF TETRAIODO (1,8-DI-2-PYRIDYL-3,6-DITHIAOCTANE-N,S,S',N')DIMERCURY(II) [J].
CASTINEIRAS, A ;
DIAZ, G ;
FLORENCIO, F ;
GARCIABLANCO, S ;
MARTINEZCARRERA, S .
JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH, 1988, 18 (04) :395-401
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