TEMPERATURE-DEPENDENCE OF BORON COORDINATION IN ALKALI BORATE GLASSES AS AN EXAMPLE OF A 2ND ORDER TRANSITION

被引:0
|
作者
ARAUJO, RJ
机构
来源
PHYSICS AND CHEMISTRY OF GLASSES | 1980年 / 21卷 / 05期
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A statistical mechanical calculation of the number of boron atoms in tetrahedral coordination in alkali borate glasses as a function of temperature and composition is presented. The entropy calculated for a fixed composition as a function of temperature shows that the system undergoes a second order transition.
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页码:193 / 196
页数:4
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