LITHIUM ANILIDE COMPLEXED BY PMDETA - EXPECTATION OF A SIMPLE MONOMER, BUT IN REALITY AN ODD TRINUCLEAR COMPOSITION COMBINING 3-COORDINATE, 4-COORDINATE AND 5-COORDINATE LITHIUM

被引：28

作者：

BARR, D

CLEGG, W

COWTON, L

HORSBURGH, L

MACKENZIE, FM

MULVEY, RE

机构：

[1] UNIV NEWCASTLE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

[2] UNIV STRATHCLYDE,DEPT PURE & APPL CHEM,GLASGOW G1 1XL,LANARK,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 08期

关键词：

D O I：

10.1039/c39950000891

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lithium structural chemistry continues to surprise as highlighted here by the reaction of Bu(n)Li, aniline and pmdeta, which by analogy with related systems, should yield a simple monomeric complex, when, in fact, an unprecedented trinuclear formulation is produced; in contrast, the corresponding Na system falls into line with predictions, in yielding a dimeric product.

引用

页码：891 / 892

页数：2

共 12 条

[1] THE DEVELOPMENT OF VERSION-3 AND VERSION-4 OF THE CAMBRIDGE STRUCTURAL DATABASE SYSTEM
ALLEN, FH
DAVIES, JE
GALLOY, JJ
JOHNSON, O
KENNARD, O
MACRAE, CF
MITCHELL, EM
MITCHELL, GF
SMITH, JM
WATSON, DG
[J]. JOURNAL OF CHEMICAL INFORMATION AND COMPUTER SCIENCES, 1991, 31 (02): : 187 - 204
[2] SYNTHETIC, STRUCTURAL, MECHANISTIC, AND THEORETICAL MO STUDIES OF THE ALKALI-METAL CHEMISTRY OF DIBENZYLAMINE AND ITS TRANSFORMATION TO 1,3-DIPHENYL-2-AZAALLYL DERIVATIVES
ANDREWS, PC
ARMSTRONG, DR
BAKER, DR
MULVEY, RE
CLEGG, W
HORSBURGH, L
ONEIL, PA
REED, D
[J]. ORGANOMETALLICS, 1995, 14 (01) : 427 - 439
[3] THE LADDERING PRINCIPLE IN LITHIUM AMIDE CHEMISTRY - THE CRYSTAL AND MOLECULAR-STRUCTURE OF THE PYRROLIDIDOLITHIUM ADDUCT [H2C(CH2)3NLI]3.MEN(CH2CH2NME2)2
ARMSTRONG, DR
BARR, D
CLEGG, W
MULVEY, RE
REED, D
SNAITH, R
WADE, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (11) : 869 - 870
[4] LADDER STRUCTURES IN LITHIUM AMIDE CHEMISTRY - SYNTHESES AND SOLID-STATE AND SOLUTION STRUCTURES OF DONOR-DEFICIENT LITHIUM PYRROLIDIDE COMPLEXES, ([H2C(CH2)3NLI]3.PMDETA)2 AND ([H2C(CH2)3NLI]2.TMEDA)2, AND ABINITIO MO CALCULATIONS PROBING RING VS LADDER VS STACK STRUCTURAL PREFERENCES
ARMSTRONG, DR
BARR, D
CLEGG, W
HODGSON, SM
MULVEY, RE
REED, D
SNAITH, R
WRIGHT, DS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (13) : 4719 - 4727
[5] [3-BROMO-2-LITHIO-1-PHENYLSULFONYLBENZOFURAN.DIISOPROPYL ETHER]2 AND 3-FLUORO-2-LITHIO-1-PHENYL-SULFONYLBENZENE.PENTAMETHYLDIETHYLENETRIAMINE - CRYSTAL-STRUCTURES OF COMPOUNDS WITH LITHIUM AND HALOGEN ON NEIGHBORING CARBON-ATOMS
BOSOLD, F
ZULAUF, P
MARSCH, M
HARMS, K
LOHRENZ, J
BOCHE, G
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (11): : 1455 - 1457
[6] THE 1ST STRUCTURALLY CHARACTERIZED SODIUM PRIMARY AMIDE COMPLEX - SYNTHESIS AND CRYSTAL-STRUCTURE OF 2-PHOC6H4NHNA.NME[(CH2)2NME2]2
CRAGGHINE, I
DAVIDSON, MG
EDWARDS, AJ
RAITHBY, PR
SNAITH, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (19): : 2901 - 2902
[7] STRUCTURES OF ORGANONITROGEN LITHIUM COMPOUNDS - RECENT PATTERNS AND PERSPECTIVES IN ORGANOLITHIUM CHEMISTRY
GREGORY, K
SCHLEYER, PV
SNAITH, R
[J]. ADVANCES IN INORGANIC CHEMISTRY, 1991, 37 : 47 - 142
[8] SYNTHESIS AND STRUCTURE OF THE LITHIUM BROMIDE PENTAMETHYLDIETHYLENETRIAMINE 1-1 ADDUCT
HALL, SR
RASTON, CL
SKELTON, BW
WHITE, AH
[J]. INORGANIC CHEMISTRY, 1983, 22 (26) : 4070 - 4073
[9] MELDOLA MEDAL LECTURE - RING-STACKING AND RING-LADDERING IN ORGANONITROGENLITHIUM COMPOUNDS - THE DEVELOPMENT OF CONCEPTS WITH WIDE APPLICABILITY THROUGHOUT LITHIUM STRUCTURAL CHEMISTRY
MULVEY, RE
[J]. CHEMICAL SOCIETY REVIEWS, 1991, 20 (02) : 167 - 209
[10] METAL-ALKYL AND METALARYL COMPOUNDS .48. SYNTHESIS AND STRUCTURE OF A PHENYLSODIUM SOLVATE, BIS[MU-PHENYL(PENTAMETHYLDIETHYLENETRIAMINE)-SODIUM
SCHUMANN, U
BEHRENS, U
WEISS, E
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (04): : 476 - 477

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