LITHIUM ANILIDE COMPLEXED BY PMDETA - EXPECTATION OF A SIMPLE MONOMER, BUT IN REALITY AN ODD TRINUCLEAR COMPOSITION COMBINING 3-COORDINATE, 4-COORDINATE AND 5-COORDINATE LITHIUM

被引：28

作者：

BARR, D

CLEGG, W

COWTON, L

HORSBURGH, L

MACKENZIE, FM

MULVEY, RE

机构：

[1] UNIV NEWCASTLE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

[2] UNIV STRATHCLYDE,DEPT PURE & APPL CHEM,GLASGOW G1 1XL,LANARK,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 08期

关键词：

D O I：

10.1039/c39950000891

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lithium structural chemistry continues to surprise as highlighted here by the reaction of Bu(n)Li, aniline and pmdeta, which by analogy with related systems, should yield a simple monomeric complex, when, in fact, an unprecedented trinuclear formulation is produced; in contrast, the corresponding Na system falls into line with predictions, in yielding a dimeric product.

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页码：891 / 892

页数：2

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