Crystal structure of (N-1-benzyl-N-1,N-2,N-2-trimethylethane-1,2-diamine-kappa N-2,N ')dichloridomercury(II)

被引：2

作者：

Manjare, Sudesh T. ^{[1
]}

Singh, Harkesh B. ^{[1
]}

Butcher, Ray J. ^{[2
]}

机构：

[1] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India

[2] Howard Univ, Dept Chem, 525 Coll St NW, Washington, DC 20059 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

关键词：

crystal structure; mercury complex; tertiary amine donors;

D O I：

10.1107/S1600536814017516

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the structure of the title compound, [HgCl2(C12H20N2)], the Hg-II atom has a distorted tetrahedral coordination sphere defined by two tertiary amine N-atom donors, as well as two Cl- anions [the dihedral angle between the N-Hg-N and Cl-Hg-Cl planes is 82.80 (9)degrees]. The five-membered chelate ring adopts an envelope conformation, with puckering parameters of Q(2) = 0.446 (6) angstrom and phi(2) = 88.8 (6)degrees, with the two amine CH3 substituents on opposite sides of the ring. In the crystal, the molecules are linked by C-H center dot center dot center dot Cl interactions into a zigzag chain parallel to [101].

引用

页码：118 / +

页数：8

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