POLY(PROPYLENE IMINE) DENDRIMERS - LARGE-SCALE SYNTHESIS BY HETEREOGENEOUSLY CATALYZED HYDROGENATIONS

被引：557

作者：

DEBRABANDERVANDENBERG, EMM ^{[1
]}

MEIJER, EW ^{[1
]}

机构：

[1] DSM RES & PATENTS,6160 MD GELEEN,NETHERLANDS

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 09期

关键词：

D O I：

10.1002/anie.199313081

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In kilogram quantities; pure poly(propylene imine) dendrimers can be prepared in an extremely simple reaction sequence comprising Michael addition (primary amines to acrylonitrile) and heterogeneous hydrogenation with a Raney cobalt catalyst. Both steps proceed quantitatively and selectively and can be employed with many core and end groups. Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1308 / 1311

页数：4

共 17 条

[1]

BUHLEIER E, 1978, SYNTHESIS-STUTTGART, P155

[2]

Goddard III W. A., 1990, ANGEW CHEM, V102, P119, DOI DOI 10.1002/ANIE.199001381

[3] PREPARATION OF POLYMERS WITH CONTROLLED MOLECULAR ARCHITECTURE - A NEW CONVERGENT APPROACH TO DENDRITIC MACROMOLECULES [J].