Crystal structure of 3-methyl-5-trimethylsilyl-1H-pyrazole

被引:1
作者
Ferrence, Gregory M. [1 ]
Kocher, Joshua L. [1 ]
机构
[1] Illinois State Univ, Dept Chem, CB 4160, Normal, IL 61790 USA
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词
crystal structure; pyrazole; tertramer; hydrogen bonding;
D O I
10.1107/S2056989015008567
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C7H14N2Si, crystallizes in a tetragonal space group and exists as an N-H center dot center dot center dot N hydrogen-bonded tetramer, formed around the crystallographic fourfold rotoinversion axis. The molecular identity is clearly the 5-trimethylsilyl-3-methyl-1H-pyrazole tautomer and the structure is isomorphous with that of 5-tert-butyl-3-methyl-1H-pyrazole [Foces-Foces & Trofimenko (2001). Acta Cryst. E57, o32-o34].
引用
收藏
页码:O397 / U255
页数:7
相关论文
共 10 条
  • [1] [Anonymous], 2008, APEX2
  • [2] NEW METHODS AND REAGENTS IN ORGANIC-SYNTHESIS .41. LITHIUM TRIMETHYLSILYLDIAZOMETHANE - A NEW SYNTHON FOR THE PREPARATION OF PYRAZOLES FROM ALPHA,BETA-UNSATURATED NITRILES
    AOYAMA, T
    INOUE, S
    SHIOIRI, T
    [J]. TETRAHEDRON LETTERS, 1984, 25 (04) : 433 - 436
  • [3] WinGX and ORTEP for Windows: an update
    Farrugia, Louis J.
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2012, 45 : 849 - 854
  • [4] 5-tert-Butyl-3-methyl-1H-pyrazole at 240 K
    Foces-Foces, CN
    Trofimenko, S
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 : O32 - O34
  • [5] The Cambridge Structural Database in Retrospect and Prospect
    Groom, Colin R.
    Allen, Frank H.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (03) : 662 - 671
  • [6] Mercury CSD 2.0 -: new features for the visualization and investigation of crystal structures
    Macrae, Clare F.
    Bruno, Ian J.
    Chisholm, James A.
    Edgington, Paul R.
    McCabe, Patrick
    Pidcock, Elna
    Rodriguez-Monge, Lucia
    Taylor, Robin
    van de Streek, Jacco
    Wood, Peter A.
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2008, 41 : 466 - 470
  • [7] SUPERFLIP -: a computer program for the solution of crystal structures by charge flipping in arbitrary dimensions
    Palatinus, Lukas
    Chapuis, Gervais
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2007, 40 : 786 - 790
  • [8] Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, 10.1107/S0108767307043930]
  • [9] Trofimenko S., 1999, SCORPIOINATES COORDI
  • [10] publCIF: software for editing, validating and formatting crystallographic information files
    Westrip, Simon P.
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2010, 43 : 920 - 925