XPS OBSERVATION OF FE1-XO AT TEMPERATURES BETWEEN 25 AND 800-DEGREES-C

被引：45

作者：

OKU, M

HIROKAWA, K

机构：

[1] Research Institute for Iron, Steel and Other Metals, Tohoku University, Sendai

来源：

JOURNAL OF APPLIED PHYSICS | 1979年 / 50卷 / 10期

关键词：

D O I：

10.1063/1.325770

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Variations of the XPS spectra of Fe1-xO crystal and iron metal oxidized in air were studied when the samples were heated in a vacuum. The structural variations observed by XPS can be explained by the phase diagram of the iron-oxygen system. The intensity ratio of O 1s to Fe 2p3/2 for Fe1-xO at 800 °C in thermal equilibrium was smaller than that of the sample quenched from 800 °C to room temperature. This indicates that quenching the sample changes the surface structure. FWHM (full width at half-maximum) of 2.2 eV of O 1s for Fe1-xO was larger than that of 1.7 eV for α-Fe2O3. The broader FWHM is due to the large value of x and clustering of the cation vacancies in Fe1-xO. The binding energies and spectral profiles of Fe 3s and Fe 2p1/2,3/2 for Fe1-xO coincided with the spectra for Fe2SiO 4 or FeTiO3 having only divalent iron ions.

引用

页码：6303 / 6308

页数：6

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