EXCITED-STATES OF THE URANYL-ION

被引：32
作者：
JORGENSEN, CK
机构：
[1] Département de Chimie minérale, analytique et appliquée, Université de Genève
来源：
JOURNAL OF LUMINESCENCE | 1979年 / 18-9卷 / JAN期
关键词：
D O I：
10.1016/0022-2313(79)90074-7
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
The first excited states are due to electron transfer, and exceptional effects of strong spin-orbit coupling and coinciding φ and δ one-electron energies in the 5f shell determine a characteristic distribution of 56 states, if one of the four πu electrons are transferred. It has no physical significance to ask whether these states are triplet or singlet. Recent Xα results are critically analyzed. Their unique photochemistry may contribute to the use of solar energy. © 1979.
引用
收藏
页码：63 / 68
页数：6
相关论文
共 32 条
[1]   ABSORPTION SPECTRUM OF URANYL ION IN PERCHLORATE MEDIA .I. MATHEMATICAL RESOLUTION OF OVERLAPPING BAND STRUCTURE AND STUDIES OF ENVIRONMENTAL EFFECTS [J].
BELL, JT ;
BIGGERS, RE .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1965, 18 (03) :247-&
[2]   PHOTOCHEMISTRY OF URANYL-ION [J].
BURROWS, HD ;
KEMP, TJ .
CHEMICAL SOCIETY REVIEWS, 1974, 3 (02) :139-165
[3]   ELECTRONIC-STRUCTURE OF URANYL-ION .1. ELECTRONIC-SPECTRUM OF CS2UO2CL4 [J].
DENNING, RG ;
SNELLGROVE, TR ;
WOODWARK, DR .
MOLECULAR PHYSICS, 1976, 32 (02) :419-442
[4]   ABSORPTION-SPECTRA OF TETRAHALODIOXOURANIUM(VI) COMPLEXES AT 4.2 DEGREES K .1. DI(TETRAMETHYLAMMONIUM)URANYLTETRACHLORIDE [J].
DISIPIO, L ;
TONDELLO, E ;
PELIZZI, G ;
INGLETTO, G ;
MONTENERO, A .
INORGANICA CHIMICA ACTA, 1977, 22 (01) :23-27
[5]  
DUFFY JA, 1977, STRUCT BOND, V32, P147
[6]  
Jorgensen C. K, 1969, OXIDATION NUMBERS OX
[7]  
Jorgensen C. K., 1971, MODERN ASPECTS LIGAN
[8]   ELECTRON TRANSFER SPECTRA OF LANTHANIDE COMPLEXES [J].
JORGENSEN, CK .
MOLECULAR PHYSICS, 1962, 5 (03) :271-277
[9]   COMPLEXES OF THE 4D-GROUPS AND 5D-GROUPS .4. ELECTRON TRANSFER BANDS WITH SPECIAL APPLICATION TO DELEPINE,M. COMPLEXES AND A TRANSITION FROM IRIDIUM(III) TO PYRIDINE, WITH SOME REMARKS ABOUT INTERMEDIATE COUPLING IN HALIDE COMPLEXES AND THE URANYL ION [J].
JORGENSEN, CK .
ACTA CHEMICA SCANDINAVICA, 1957, 11 (01) :166-178
[10]  
JORGENSEN CK, 1963, ADV CHEM PHYS, V5, P33
1234