ENANTIOSELECTIVE CATALYSIS .66. ENANTIOSELECTIVE CATALYTIC TRANSFER HYDROGENATION OF ALPHA,BETA-UNSATURATED CARBOXYLIC-ACIDS WITH FORMATES CATALYZED BY NOVEL RUTHENIUM PHOSPHINE COMPLEXES

被引：61

作者：

BROWN, JM ^{[1
]}

BRUNNER, H ^{[1
]}

LEITNER, W ^{[1
]}

ROSE, M ^{[1
]}

机构：

[1] UNIV REGENSBURG,INST ANORGAN CHEM,W-8400 REGENSBURG,GERMANY

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 05期

关键词：

D O I：

10.1016/S0957-4166(00)82111-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrogen transfer from the formic acid/triethylamine (5:2) azeotrope to alpha,beta-unsaturated carboxylic acids is effectively catalyzed by ruthenium complexes of general formula [Ru(acac-F6)(eta-3 - C3H5)(diphosphine)]. If a chiral diphosphine is employed, the saturated acids are obtained in up to 93% ee, the most active and selective catalyst being formed with BINAP.

引用

页码：331 / 334

页数：4

共 49 条

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[32] BINUCLEAR COPPER(II) COMPLEXES WITH ALPHA,BETA-UNSATURATED CARBOXYLIC-ACIDS .1. COPPER ACRYLATES WITH HETEROCYCLIC AMINE ADDUCTS
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[33] Ruthenium-Catalyzed Chemoselective Olefin Transfer Hydrogenation of alpha, beta-Unsaturated Carbonyl Systems By Using EtOH as Hydrogen Source
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TETRAHEDRON LETTERS, 1982, 23 (37) : 3819 - 3822
[35] Substrate effects on the mechanism of enantioselective hydrogenation using ruthenium bis(phosphine) complexes as catalyst:: A mechanistic investigation of the hydrogenation of α,β-unsaturated acids and esters based on deuterium labeling studies
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Wiles, Jason A.
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INORGANICA CHIMICA ACTA, 2006, 359 (09) : 2760 - 2770
[36] HOMOGENEOUS HYDROGENATION OF ALPHA, BETA-UNSATURATED KETONES AND ALDEHYDES CATALYZED BY CO2(CO)8-DI(TERTIARY PHOSPHINE) COMPLEXES
MURATA, K
MATSUDA, A
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1981, 54 (06) : 1899 - 1900
[37] ENANTIOSELECTIVE CATALYSIS .6. THE CATALYTIC-HYDROGENATION OF ALPHA-(ACETYLAMINO)CINNAMIC ACID WITH RHODIUM(I)-BIS(PHOSPHINE) COMPLEXES - ON THE ORIGIN OF THE ENANTIOSELECTION
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RIEGER, B
ORGANOMETALLICS, 1989, 8 (06) : 1534 - 1538
[38] Enantioselective transfer hydrogenation of pro-chiral ketones catalyzed by novel ruthenium and iridium complexes of well-designed phosphinite ligand
Arslan, Nevin
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2020, 195 (08) : 628 - 637
[39] ENANTIOSELECTIVE HYDROGENATION OF BETA-DISUBSTITUTED ALPHA-ACETAMIDOACRYLATES CATALYZED BY RHODIUM COMPLEXES WITH TRAP TRANS-CHELATING CHIRAL PHOSPHINE-LIGANDS
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[40] Enantioselective hydrogenation of alpha,beta-unsaturated acids. Substrate-modifier interaction over cinchonidine modified Pd/Al2O3
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Baiker, A
TETRAHEDRON-ASYMMETRY, 1997, 8 (22) : 3745 - 3753

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