ENANTIOSELECTIVE CATALYSIS .66. ENANTIOSELECTIVE CATALYTIC TRANSFER HYDROGENATION OF ALPHA,BETA-UNSATURATED CARBOXYLIC-ACIDS WITH FORMATES CATALYZED BY NOVEL RUTHENIUM PHOSPHINE COMPLEXES

被引：61

作者：

BROWN, JM ^{[1
]}

BRUNNER, H ^{[1
]}

LEITNER, W ^{[1
]}

ROSE, M ^{[1
]}

机构：

[1] UNIV REGENSBURG,INST ANORGAN CHEM,W-8400 REGENSBURG,GERMANY

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 05期

关键词：

D O I：

10.1016/S0957-4166(00)82111-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrogen transfer from the formic acid/triethylamine (5:2) azeotrope to alpha,beta-unsaturated carboxylic acids is effectively catalyzed by ruthenium complexes of general formula [Ru(acac-F6)(eta-3 - C3H5)(diphosphine)]. If a chiral diphosphine is employed, the saturated acids are obtained in up to 93% ee, the most active and selective catalyst being formed with BINAP.

引用

页码：331 / 334

页数：4

共 49 条

[1] ENANTIOSELECTIVE CATALYSIS .43. ENANTIOSELECTIVE CATALYTIC TRANSFER-HYDROGENATION OF ALPHA,BETA-UNSATURATED CARBOXYLIC-ACIDS WITH TRIETHYLAMMONIUM FORMATE
BRUNNER, H
LEITNER, W
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1988, 27 (09) : 1180 - 1181
[2] ASYMMETRIC SYNTHESIS BY CHIRAL RUTHENIUM COMPLEXES .2. ENANTIOSELECTIVE HYDROGENATION OF ALPHA,BETA-UNSATURATED CARBOXYLIC-ACIDS CATALYZED BY RUTHENIUM COMPLEXES CONTAINING LIGAND (-)-DIOP
BOTTEGHI, C
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JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 140 (02) : 221 - 228
[3] Rhodium and ruthenium catalyzed enantioselective transfer hydrogenation of α,β-unsaturated carboxylic acids.
Tellers, DM
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McWilliams, JC
Sun, YK
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U32 - U32
[4] HIGHLY ENANTIOSELECTIVE HYDROGENATION OF ALPHA-BETA-UNSATURATED CARBOXYLIC-ACIDS CATALYZED BY H(8)-BINAP-RU(II) COMPLEXES
ZHANG, XY
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MATSUMURA, K
SAYO, N
KUMOBAYASHI, H
TAKAYA, H
SYNLETT, 1994, (07) : 501 - 503
[5] MECHANISTIC ASPECTS OF THE RHODIUM-CATALYZED ENANTIOSELECTIVE TRANSFER HYDROGENATION OF ALPHA,BETA-UNSATURATED CARBOXYLIC-ACIDS USING FORMIC-ACID TRIETHYLAMINE (5-2) AS THE HYDROGEN SOURCE
LEITNER, W
BROWN, JM
BRUNNER, H
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (01) : 152 - 159
[6] NOVEL DISTANNOXANE-CATALYZED TRANSESTERIFICATION AND A NEW ENTRY TO ALPHA,BETA-UNSATURATED CARBOXYLIC-ACIDS
OTERA, J
YANO, T
KAWABATA, A
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TETRAHEDRON LETTERS, 1986, 27 (21) : 2383 - 2386
[7] ASYMMETRIC HYDROGENATION OF UNSATURATED CARBOXYLIC-ACIDS CATALYZED BY BINAP-RUTHENIUM(II) COMPLEXES
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TAKAYA, H
KITAMURA, M
NAGAI, K
NOYORI, R
JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (14): : 3174 - 3176
[8] OXIDATIVE TRANSFER DEHYDROGENATION OF ALPHA,BETA-UNSATURATED CARBINOLS TO ALPHA,BETA-UNSATURATED KETONES CATALYZED BY RUTHENIUM COMPLEXES
SASSON, Y
REMPEL, GL
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1974, 52 (22): : 3825 - 3827
[9] HOMOGENEOUS HYDROGENATION OF ALPHA,BETA-UNSATURATED ALDEHYDES CATALYZED BY RUTHENIUM AND OSMIUM COMPLEXES
SANCHEZDELGADO, RA
ANDRIOLLO, A
VALENCIA, N
JOURNAL OF MOLECULAR CATALYSIS, 1984, 24 (02): : 217 - 220
[10] HYDROGENATION OF ALPHA,BETA-UNSATURATED ALDEHYDES AND KETONES TO THE UNSATURATED ALCOHOLS CATALYZED BY HYDRIDOIRIDIUM PHOSPHINE COMPLEXES
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KASPAR, J
SPOGLIARICH, R
GRAZIANI, M
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (10) : 746 - 747

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