THERMOCHROMISM AND THERMAL E,Z ISOMERIZATIONS IN BIANTHRONES

被引：58

作者：

TAPUHI, Y ^{[1
]}

KALISKY, O ^{[1
]}

AGRANAT, I ^{[1
]}

机构：

[1] HEBREW UNIV JERUSALEM,DEPT PHYS CHEM,JERUSALEM 91000,ISRAEL

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 12期

关键词：

D O I：

10.1021/jo01326a012

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The standard heat of the thermochromic equilibrium A⇋B in bianthrones (1) was investigated in the temperature range 40-220μC, with special emphasis on steric effects. The data indicate that there is no direct correlation between Δvalues and possible steric interactions in the vicinity of the central double bond. The thermal decay of the colored B species of 2, 2ʹ-bis(trifluoromethyl)bianthrone (3) was studied by laser flash photolysis. The relation between the thermochromic process and the fast thermal E, Z isomerization found in the bianthrone series is discussed. It is concluded that both thermal phenomena have a common transition state. © 1979, American Chemical Society. All rights reserved.

引用

页码：1949 / 1952

页数：4