HEXAGONAL INDIUM TUNGSTEN BRONZE

被引：23
作者：
BOUCHARD, RJ
GILLSON, JL
机构：
[1] Central Research Department, Experimental Station, E. I. du Pont de Nemours and Company, Wilmington
来源：
INORGANIC CHEMISTRY | 1968年 / 7卷 / 05期
关键词：
D O I：
10.1021/ic50063a025
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The electrical resistivity of single crystals of hexagonal InxWO3 (x = 0.21-0.27) has been measured both perpendicular to and parallel with the c axis. Nearly isotropic metallic behavior was found. Seebeck voltages were small and negative, while magnetic susceptibility measurements showed isotropic diamagnetism. These results are consistent with covalent t2g-pπ bonding and the formation of a π* band. © 1968, American Chemical Society. All rights reserved.
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页码：969 / &
相关论文
共 17 条
[1]   SUPERCONDUCTIVITY OF SOME NEW HEXAGONAL TUNGSTEN BRONZES [J].
BIERSTEDT, PE ;
BITHER, TA ;
DARNELL, FJ .
SOLID STATE COMMUNICATIONS, 1966, 4 (01) :25-+
[2]   SYNTHESIS OF MOLYBDENUM AND TUNGSTEN BRONZES AT HIGH PRESSURE [J].
BITHER, TA ;
GILLSON, JL ;
YOUNG, HS .
INORGANIC CHEMISTRY, 1966, 5 (09) :1559-&
[3]   LANTHANUM AND YTTRIUM TUNGSTEN BRONZES [J].
BROYDE, B .
INORGANIC CHEMISTRY, 1967, 6 (08) :1588-&
[4]   RELATION OF ELECTRICAL CONDUCTIVITY IN SINGLE CRYSTALS OF RHENIUM TRIOXIDE TO CONDUCTIVITIES OF SR2MGREO6 AND NACHIWO3 [J].
FERRETTI, A ;
ROGERS, DB ;
GOODENOUGH, JB .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1965, 26 (12) :2007-+
[5]  
GAOD P, 1966, MATER RES B, V1, P33
[6]  
GIER TE, TO BE PUBLISHED
[7]  
GOODENOUGH JB, 1965, B SOC CHIM FR, V4, P1200
[8]   The spinels and the cubic sodium-tungsten bronzes as new examples of structures with vacant lattice points [J].
Hagg, G .
NATURE, 1935, 135 :874-874
[9]  
ISUPOV VA, 1963, SOV PHYS-CRYSTALLOGR, V8, P81
[10]   WO3 - SEINE ZUCHTUNG UND KRISTALLOGRAPHISCHE UNTERSUCHUNG [J].
KLEBER, W ;
HAHNERT, M ;
MULLER, R .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1966, 346 (3-4) :113-&
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