RAMAN-SPECTROSCOPIC STUDY OF THE MOLECULAR-CONFORMATION OF ALPHA-OCTYL-OMEGA-METHOXYOLIGO(OXYETHYLENE)S IN THE SOLID-STATE

被引：9

作者：

MASATOKI, S ^{[1
]}

MATSUURA, H ^{[1
]}

FUKUHARA, K ^{[1
]}

机构：

[1] HIROSHIMA UNIV,FAC SCI,DEPT CHEM,HIROSHIMA 730,JAPAN

来源：

JOURNAL OF RAMAN SPECTROSCOPY | 1994年 / 25卷 / 7-8期

关键词：

D O I：

10.1002/jrs.1250250726

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The Raman spectra of alpha-octyl-omega-methoxyoligo(oxyethylene)s, CH3(CH2)7(OCH2CH2)mOCH3 (m = 1-4), were measured in the solid state. The molecular conformation of these compounds was determined by a spectral analysis based on the key conformational bands. The conformation of the inner oxyethylene segments changes from an extended structure to a helical structure as the number of oxyethylene units increases. The difference in the conformational behaviour between the present methoxy-ended compounds and the corresponding hydroxy-ended compounds is associated with the different layer structures of the crystals.

引用

页码：641 / 645

页数：5

共 50 条

[41] Vibrational dynamics and hydrogen bond properties of β-CD nanosponges: an FTIR-ATR, Raman and solid-state NMR spectroscopic study
Castiglione, F.
Crupi, V.
Majolino, D.
Mele, A.
Panzeri, W.
Rossi, B.
Trotta, F.
Venuti, V.
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2013, 75 (3-4) : 247 - 254
[42] Vibrational dynamics and hydrogen bond properties of β-CD nanosponges: an FTIR-ATR, Raman and solid-state NMR spectroscopic study
F. Castiglione
V. Crupi
D. Majolino
A. Mele
W. Panzeri
B. Rossi
F. Trotta
V. Venuti
Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2013, 75 : 247 - 254
[43] CONFORMATION AND DYNAMICS OF (1-]3)-BETA-D-GLUCANS IN THE SOLID AND GEL STATE - HIGH-RESOLUTION SOLID-STATE C-13 NMR SPECTROSCOPIC STUDY
SAITO, H
ACS SYMPOSIUM SERIES, 1992, 489 : 296 - 310
[44] SOLID-STATE STUDIES .26. RAMAN-SPECTROSCOPIC EVIDENCE FOR A PHASE II-LIKE INTERMEDIATE DURING THE COURSE OF THE IV-III-PHASE TRANSITION IN AMMONIUM-NITRATE
KEARLEY, GJ
KETTLE, SFA
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1982, 78 : 3691 - 3692
[45] INFLUENCE OF MOLECULAR-CONFORMATION ON SOLID-STATE PACKING OF 1,2-DIGLYCERIDES - STUDY OF 1,2-DIPALMITIN AND SOME STRUCTURAL ANALOGS BY ELECTRON-DIFFRACTION, X-RAY-DIFFRACTION, AND INFRARED SPECTROSCOPY
DORSET, DL
PANGBORN, WA
HANCOCK, AJ
LEE, IS
ZEITSCHRIFT FUR NATURFORSCHUNG C-A JOURNAL OF BIOSCIENCES, 1978, 33 (1-2): : 39 - 49
[46] IR SPECTROSCOPIC STUDY OF HYDROGEN-BONDS IN PERMETHYLATED ALPHA-METALLOCENYLCARBINOLS IN THE SOLID-STATE (M = FE, RU, OS)
SHUBINA, ES
EPSTEIN, LM
KREINDLIN, AZ
FADEEVA, SS
RYBINSKAYA, MI
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 401 (1-2) : 145 - 153
[47] TEMPERATURE-DEPENDENCE OF MOLECULAR-CONFORMATION IN SOLID-STATE PHASE-TRANSFORMATIONS OF N-BASE ADDUCTS OF BIS(1,5-CYCLOOCTANEDIYL)DIBOROXANE BY X-RAY-DIFFRACTION
YALPANI, M
KOSTER, R
BOESE, R
SULKOWSKI, M
CHEMISCHE BERICHTE, 1989, 122 (01) : 9 - 17
[48] The conformation of the Congo-red ligand bound to amyloid fibrils HET-s(218–289): a solid-state NMR study
Chandrakala Gowda
Giorgia Zandomeneghi
Herbert Zimmermann
Anne K. Schütz
Anja Böckmann
Matthias Ernst
Beat H. Meier
Journal of Biomolecular NMR, 2017, 69 : 207 - 213
[49] A variable temperature solid-state nuclear magnetic resonance, electron paramagnetic resonance and Raman scattering study of molecular dynamics in ferroelectric fluorides
Kowalczyk, Radoslaw M.
Kemp, Thomas F.
Walker, David
Pike, Kevin J.
Thomas, Pamela A.
Kreisel, Jens
Dupree, Ray
Newton, Mark E.
Hanna, John V.
Smith, Mark E.
JOURNAL OF PHYSICS-CONDENSED MATTER, 2011, 23 (31)
[50] ARCHITECTURE OF THE ORGANOMETALLIC ION-EXCHANGERS [(ME3SNIV)4MII(CN)6]INFINITY(M = FE, RU, OS) - A COMBINED MULTINUCLEAR SOLID-STATE MAGNETIC-RESONANCE AND INFRARED RAMAN-SPECTROSCOPIC STUDY
ELLER, S
SCHWARZ, P
BRIMAH, AK
FISCHER, RD
APPERLEY, DC
DAVIES, NA
HARRIS, RK
ORGANOMETALLICS, 1993, 12 (08) : 3232 - 3240

← 1 2 3 4 5 →