PENDANT-FUNCTIONALIZED LIGANDS FOR METALLOSUPRAMOLECULAR ASSEMBLIES - RUTHENIUM(II) AND OSMIUM(II) COMPLEXES OF 4'-(4-PYRIDYL)-2,2'/6',2''-TERPYRIDINE

被引：135

作者：

CONSTABLE, EC ^{[1
]}

THOMPSON, AMWC ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CAMBRIDGE CTR MOLEC RECOGNIT,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 09期

关键词：

D O I：

10.1039/dt9940001409

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The potentially tetradentate ligand 4'-(4-pyridyl)-2,2':6',2''-terpyridine (pyterpy) acts as a tridentate donor to iron(II), ruthenium(II) and osmium(II). The non-co-ordinated pyridyl group reacts with a range of electrophiles to give complexes containing the cationic ligands Hpyterpy and 4'-(4-methylpyridinio)-2,2':6',2'-terpyridine (mpyterpy). The electrochemical behaviour of these complexes has been studied and correlations between the redox potentials and Hammett sigma+ parameters made.

引用

页码：1409 / 1418

页数：10

共 18 条

[1] DIRECTIVE EFFECTS IN AROMATIC SUBSTITUTION .30. ELECTROPHILIC SUBSTITUENT CONSTANTS [J].

BROWN, HC ;

OKAMOTO, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (18) :4979-4987

[2] A NEW HETERO-TETRAMETALLIC COMPLEX OF RUTHENIUM AND OSMIUM - ABSORPTION-SPECTRUM, LUMINESCENCE PROPERTIES, AND ELECTROCHEMICAL-BEHAVIOR [J].

CAMPAGNA, S ;

DENTI, G ;

SABATINO, L ;

SERRONI, S ;

CIANO, M ;

BALZANI, V .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (19) :1500-1501

[3] NOVEL SYNTHESIS OF A DOUBLY CYCLOMETALATED DIRUTHENIUM COMPLEX WITH STRONGLY COUPLED METAL CENTERS [J].

CONSTABLE, EC ;

THOMPSON, AMWC ;

GREULICH, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (18) :1444-1446

[4] MULTINUCLEATING 2,2'/6',2''-TERPYRIDINE LIGANDS AS SUPRAMOLECULAR BUILDING-BLOCKS - HETEROTRINUCLEAR COMPLEXES AND THE CRYSTAL AND MOLECULAR-STRUCTURE OF 6',6''-BIS(2-PYRIDYL)-2,2'/4',4''/2'',2'''-QUATERPYRIDINE (BTPY) [J].

CONSTABLE, EC ;

THOMPSON, AMWC ;

TOCHER, DA .

SUPRAMOLECULAR CHEMISTRY, 1993, 3 (01) :9-14

[5] THE ELECTRONIC-STRUCTURE OF SOME RUTHENIUM(II) COMPLEXES RELATED TO [RU(BIPY)3]2+ - AN INVESTIGATION OF THE STEPWISE REPLACEMENT OF N,N-DONORS BY C,N-DONORS [J].

CONSTABLE, EC ;

HOUSECROFT, CE .

POLYHEDRON, 1990, 9 (15-16) :1939-1947

[6] LIGAND SUBSTITUTION PATTERNS CONTROL PHOTOPHYSICAL PROPERTIES OF RUTHENIUM(II)-2,2',/6',2''-TERPYRIDINE COMPLEXES - ROOM-TEMPERATURE EMISSION FROM [RU(TPY)2]2+ ANALOGS [J].

CONSTABLE, EC ;

THOMPSON, AMWC ;

ARMAROLI, N ;

BALZANI, V ;

MAESTRI, M .

POLYHEDRON, 1992, 11 (20) :2707-2709

[7] THE COORDINATION CHEMISTRY OF 2,2'-6',2''-TERPYRIDINE AND HIGHER OLIGOPYRIDINES [J].

CONSTABLE, EC .

ADVANCES IN INORGANIC CHEMISTRY, 1986, 30 :69-121

[8]

CONSTABLE EC, 1992, NEW J CHEM, V16, P855

[9] COMPLEXES CONTAINING FERROCENYL GROUPS AS REDOX SPECTATORS - SYNTHESIS, MOLECULAR-STRUCTURE AND COORDINATION BEHAVIOR OF 4'-FERROCENYL-2,2'/6',2''-TERPYRIDINE [J].

CONSTABLE, EC ;

EDWARDS, AJ ;

MARTINEZMANEZ, R ;

RAITHBY, PR ;

THOMPSON, AMWC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (05) :645-650

[10] THE 1ST STRUCTURALLY CHARACTERIZED HETERODINUCLEAR DOUBLE-HELICATE COMPLEX [J].

CONSTABLE, EC ;

EDWARDS, AJ ;

RAITHBY, PR ;

WALKER, JV .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (10) :1465-1467

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