SYNTHESIS, CRYSTAL, AND MOLECULAR-STRUCTURE OF THE PALLADIUM(0)-FULLERENE DERIVATIVE (ETA-2-C60)PD(PPH3)2

被引：134
作者：
BASHILOV, VV
PETROVSKII, PV
SOKOLOV, VI
LINDEMAN, SV
GUZEY, IA
STRUCHKOV, YT
机构：
[1] Institute of Organo-Element Compounds, Academy of Sciences of Russia, Moscow 117813
来源：
ORGANOMETALLICS | 1993年 / 12卷 / 04期
关键词：
D O I：
10.1021/om00028a003
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Buckminsterfullerene, C60, reacts with Pd-(PPh3)4 in solution to give in high yield a palladium(0) complex, (C60)Pd(PPh3)z in which fullerene is ligated in a eta2 fashion. The molecular structure of this compound has been established by the X-ray study of a single crystal.
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页码：991 / 992
页数：2
相关论文
共 17 条
[1]   (ETA-2-C70)IR(CO)CL(PPH3)2 - THE SYNTHESIS AND STRUCTURE OF AN ORGANOMETALLIC DERIVATIVE OF A HIGHER FULLERENE [J].
BALCH, AL ;
CATALANO, VJ ;
LEE, JW ;
OLMSTEAD, MM ;
PARKIN, SR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (23) :8953-8955
[2]   SUBSTITUTED C-60 MOLECULES - A STUDY IN SYMMETRY REDUCTION [J].
CHASE, B ;
FAGAN, PJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (06) :2252-2256
[3]   THE CHEMICAL NATURE OF BUCKMINSTERFULLERENE (C60) AND THE CHARACTERIZATION OF A PLATINUM DERIVATIVE [J].
FAGAN, PJ ;
CALABRESE, JC ;
MALONE, B .
SCIENCE, 1991, 252 (5009) :1160-1161
[4]  
FAGAN PJ, 1992, ACS SYM SER, V481, P177
[5]   METAL-COMPLEXES OF BUCKMINSTERFULLERENE (C-60) [J].
FAGAN, PJ ;
CALABRESE, JC ;
MALONE, B .
ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (03) :134-142
[6]   CRYSTAL-STRUCTURE OF OSMYLATED C60 - CONFIRMATION OF THE SOCCER BALL FRAMEWORK [J].
HAWKINS, JM ;
MEYER, A ;
LEWIS, TA ;
LOREN, S ;
HOLLANDER, FJ .
SCIENCE, 1991, 252 (5003) :312-313
[7]   PREPARATION OF FULLERENES WITH A SIMPLE BENCHTOP REACTOR [J].
KOCH, AS ;
KHEMANI, KC ;
WUDL, F .
JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (14) :4543-4545
[8]  
KOEFOD RS, 1991, J AM CHEM SOC, V113, P8957, DOI 10.1021/ja00023a060
[9]   SOLID C-60 - A NEW FORM OF CARBON [J].
KRATSCHMER, W ;
LAMB, LD ;
FOSTIROPOULOS, K ;
HUFFMAN, DR .
NATURE, 1990, 347 (6291) :354-358
[10]   C-60 - BUCKMINSTERFULLERENE [J].
KROTO, HW ;
HEATH, JR ;
OBRIEN, SC ;
CURL, RF ;
SMALLEY, RE .
NATURE, 1985, 318 (6042) :162-163
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