REDUCTION OF TELLURIUM BY NA2[FE(CO)4] - SYNTHESIS AND REACTIVITY OF [PPN]2[FE2(CO)6(TE2)2]

被引：45

作者：

BACHMAN, RE ^{[1
]}

WHITMIRE, KH ^{[1
]}

机构：

[1] RICE UNIV, DEPT CHEM, POB 1892, HOUSTON, TX 77251 USA

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 05期

关键词：

D O I：

10.1021/om00029a068

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[PPN]2[Fe2(CO)6(Te2)27 was synthesized by the direct reaction of Na2Fe(CO)4 with elemental tellurium. Reaction of [PPN]2[Fe2(CO)6(Te2)2] with iodomethane or diiodomethane yielded Fe2(CO)6(mu-TeMe)2, which was structurally characterized, or the known Fe2-(CO)6(Te)2(mu-CH2), respectively.

引用

页码：1988 / 1992

页数：5

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