REDUCTION OF TELLURIUM BY NA2[FE(CO)4] - SYNTHESIS AND REACTIVITY OF [PPN]2[FE2(CO)6(TE2)2]

被引：45

作者：

BACHMAN, RE ^{[1
]}

WHITMIRE, KH ^{[1
]}

机构：

[1] RICE UNIV, DEPT CHEM, POB 1892, HOUSTON, TX 77251 USA

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 05期

关键词：

D O I：

10.1021/om00029a068

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[PPN]2[Fe2(CO)6(Te2)27 was synthesized by the direct reaction of Na2Fe(CO)4 with elemental tellurium. Reaction of [PPN]2[Fe2(CO)6(Te2)2] with iodomethane or diiodomethane yielded Fe2(CO)6(mu-TeMe)2, which was structurally characterized, or the known Fe2-(CO)6(Te)2(mu-CH2), respectively.

引用

页码：1988 / 1992

页数：5

共 36 条

[1] GROUP-10 TELLURIDE AND POLYTELLURIDE COMPLEXES - SYNTHESIS AND STRUCTURES OF PD(TE4)22- AND (PH3P)2PT(MU-TE)2PT(PPH3)2 [J].

ADAMS, RD ;

WOLFE, TA ;

EICHHORN, BW ;

HAUSHALTER, RC .

POLYHEDRON, 1989, 8 (05) :701-703

[2]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV, p[99, 149]

[3] SYNTHESIS OF HETEROMETALLIC CLUSTER COMPOUNDS FROM FE3(MU-3-TE)2(CO)9 AND COMPARISONS WITH ANALOGOUS SULFIDE CLUSTERS [J].

BOGAN, LE ;

LESCH, DA ;

RAUCHFUSS, TB .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 250 (01) :429-438

[4] SYNTHESIS OF ACETYLENE ADDUCTS OF AN IRON MOLYBDENUM CLUSTER THROUGH TRAPPING EXPERIMENTS ON (C5H5)2MO2FETE2(CO)X - CONVERSION OF ARACHNO-(C5H5)2MO2FETE2(CO)7 TO CLOSO-(C5H5)2MO2FETE2(CO)3(RC2H) [J].

BOGAN, LE ;

CLARK, GR ;

RAUCHFUSS, TB .

INORGANIC CHEMISTRY, 1986, 25 (22) :4050-4052

[5] STEREOCHEMICAL ANALYSIS OF FE2(CO)6(MU-SE2) - DISELENIUM ANALOG OF FE2(CO)6(MU-S2) [J].

CAMPANA, CF ;

LO, FYK ;

DAHL, LF .

INORGANIC CHEMISTRY, 1979, 18 (11) :3060-3064

[6]

COTTON FA, 1974, INORG CHIM ACTA, V11, P29

[7] STRUCTURE AND NATURE OF BONDING OF [C2H5SFE(CO)3]2 [J].

DAHL, LF ;

WEI, CH .

INORGANIC CHEMISTRY, 1963, 2 (02) :328-&

[8]

DRAGO RS, 1977, PHYSICAL METHODS CHE, P218

[9] SYNTHESIS, STRUCTURE, AND PROPERTIES OF FE2TE3(CO)62- CONTAINING THE UNUSUAL MU-2-ETA-1-TE22- LIGAND [J].

EICHHORN, BW ;

HAUSHALTER, RC ;

MEROLA, JS .

INORGANIC CHEMISTRY, 1990, 29 (04) :728-731

[10] SYNTHESIS AND STRUCTURE OF CLOSO-SN9CR(CO)34- - THE 1ST MEMBER IN A NEW CLASS OF POLYHEDRAL CLUSTERS [J].

EICHHORN, BW ;

HAUSHALTER, RC ;

PENNINGTON, WT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (26) :8704-8706

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