TRIAZOLOPYRIDINES .14. SUBSTITUTION-REACTIONS OF 7-AMINO[1,2,3]TRIAZOLO[1,5-A]PYRIDINES

被引：4
作者：
ASENSIO, A
ABARCA, B
JONES, G
HURSTHOUSE, MB
MALIK, KMA
机构：
[1] UNIV KEELE,DEPT CHEM,KEELE ST5 5BG,STAFFS,ENGLAND
[2] UNIV VALENCIA,FAC FARM,DEPT QUIM ORGAN,E-46010 VALENCIA,SPAIN
[3] UNIV WALES COLL CARDIFF,SCH CHEM & APPL CHEM,SERC,XRAY CRYSTALLOG UNIT,CARDIFF CF1 3TB,WALES
来源：
TETRAHEDRON | 1993年 / 49卷 / 03期
关键词：
AMINOTRIAZOLOPYRIDINES; AMBIDENT ANIONS; ALKYLATION ACYLATION; TRIAZOLYALKENYL CYANIDES; X-RAY DIFFRACTION;
D O I：
10.1016/S0040-4020(01)86272-4
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Reaction between 7-aminotriazolopyridines 1 or 2 and sulphuric acid gives hydroxyalklpyridines 3 and 4 ; bromination gives brominated pyridine 5 or triazolopyridine 6. The anions from amines 1 or 2 are ambident, acylating on N but alkylating on N or on C6; in the latter case triazolylalkenylcyanides 16 - 20 or the 6,6-dialkylated derivative 19 are obtained An X-ray diffraction study has confirmed structure 19.
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收藏
页码：703 / 712
页数：10
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