Some considerations related to the use of the Scherrer equation in powder X-ray diffraction as applied to heterogeneous catalysts

被引：153

作者：

Hargreaves, J. S. J. ^{[1
]}

机构：

[1] Univ Glasgow, Sch Chem, WestCHEM, Joseph Black Bldg, Glasgow G12 8QQ, Lanark, Scotland

来源：

CATALYSIS STRUCTURE & REACTIVITY | 2016年 / 2卷 / 1-4期

关键词：

Scherrer equation; Crystallite size; Williamson-Hall; Microstrain;

D O I：

10.1080/2055074X.2016.1252548

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This short overview summarises some of the basic considerations which should be undertaken when the Scherrer equation is applied to reflection widths in X-ray diffraction patterns of heterogeneous catalysts in order to extract meaningful information. Frequently, little account has been taken of the apparent complications arising from the presence of microstructural strain and disorder such as that which can be introduced upon doping or of anisotropic effects and such considerations are highlighted.

引用

页码：33 / 37

页数：5

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