SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE BENT NITROSYL ORGANOMETALLIC COMPLEX [NBU4][PT(C6CL5)2CL2(NO)]

被引：7

作者：

FORNIES, J

MENJON, B

SANZCARRILLO, RM

TOMAS, M

机构：

来源：

CHEMISCHE BERICHTE | 1994年 / 127卷 / 04期

关键词：

PLATINUM COMPLEXES; 5-COORDINATE; NITROSYL COMPLEXES;

D O I：

10.1002/cber.19941270412

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title complex has been prepared in 36% yield by reaction of [NBu4]2[trans-Pt(C6Cl5)2Cl2] with NOClO4 (1:1) in CH2Cl2. The anion exhibits an almost tetragonal-pyramidal geometry (X-ray analysis), the platinum atom being virtually located in the basal plane and the NO ligand occupying the apical position. The Pt-N-0 unit is bent [119.5(8)-degrees).

引用

页码：651 / 652

页数：2

共 29 条

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[2] Synthesis, characterisation and NMR study of paramagnetic heteropolynuclear anionic Pt-Co species. Crystal structures of [NBu4](2)[{cis-Pt(C6F5)(2)(C CSiMe3)(2)}CoCl2]center dot 0.5(CH3)(2)CO and [NBu4](2)[{Pt(C(CBu)-Bu-t)(4)}{CoCl2}(2)]center dot 1.5(CH3)(2)CO
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Fornies, J
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[3] Bridging bonding mode in a metal-pteridine complex.: Synthesis and structural characterization of Pt2Cl4 (Hmp)2 (Hmp=4-hydroxy-2-mercaptopteridine)
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INORGANIC CHEMISTRY COMMUNICATIONS, 2000, 3 (05) : 231 - 233
[4] PENTAHALOPHENYL ETHYLXANTHATE COMPLEXES OF PLATINUM(II) - STRUCTURES OF (NBU(4))[PT(C6F5)(2)(S(2)COET)] AND (NBU(4))(2)(PT-4(C6F5)(8)[(MU(3)-S)SCOET](2)) - UNPRECEDENTED COORDINATION OF THE XANTHATE LIGANDS IN THE TETRANUCLEAR COMPLEX
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INORGANICA CHIMICA ACTA, 1995, 232 (1-2) : 35 - 42
[5] A novel Trans-Pt(II) complex bearing 2-acetoxymethylbenzimidazole as a non-leaving ligand (trans-[Pt(AMBi)2Cl2]): Synthesis, antiproliferative activity, DNA interaction and molecular docking studies compared with its cis isomer (cis-[Pt(AMBi)2Cl2])
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[6] Ureato(1-) complexes of palladium(II) and platinum(II) Crystal structure of [NBu4][(C6F5)2Pt{PhNC(O)NPr2i}]
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INORGANICA CHIMICA ACTA, 1997, 264 (1-2) : 297 - 303
[8] Unexpected synthesis and structural characterization of Pt( II)Cl2-1,5-hexadiene from reaction of allyl chloride and K2PtCl4
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[9] Synthesis and crystal structure of a dinuclear platinum(II) bis(N,N-diethylamino)carbeniumdithiocarboxylate complex Pt2{μ-(Et2N)2C2S2}2Cl4•0.5CH2Cl2:: structural study of the coordinated inner salt
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INORGANICA CHIMICA ACTA, 1998, 283 (01) : 256 - 259
[10] Study of the aqueous reactions of K[Pt(Ph2SO)Cl-3] with nitrile ligands and crystal structures of N(C4H9)(4)[Pt(Ph2SO)Cl-3], N(C2H5)(4)[Pt(Ph2SO)Br-3] and cis-Pt(Ph2SO)(C3H5CN)Cl-2
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INORGANICA CHIMICA ACTA, 1997, 264 (1-2) : 89 - 100

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