COMPLEXES OF ESCULETIN WITH 2ND AND 3RD ROW TRANSITION-ELEMENTS

被引：26
作者：
GRIFFITH, WP
MOSTAFA, SI
机构：
[1] Department of Chemistry, Imperial College of Science, Technology and Medicine, London
来源：
POLYHEDRON | 1992年 / 11卷 / 08期
关键词：
D O I：
10.1016/S0277-5387(00)83334-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new esculetin (H2esc; 6,7-dihydroxy coumarin) complexes cis-[MO2(esc)2]2-, [M2O5(esc)2]2- (M = Mo, W), trans-[UO2(esc).MeOH], trans-[OsO2(esc)2]2-, [M(esc)3]2-(M = Os, Re, Ir), [M(esc)3]3- (M = Fe, Rh), [Ru(bipy)(esc)2], [ML(esc)] [M = Pd, Pt; L = (PPh3)2, bipy] and [ReOI(PPh3)2(esc)] have been prepared. Their Raman, IR, H-1 and C-13 NMR and mass spectra have been measured, and cyclic voltammograms of some of them recorded.
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页码：871 / 877
页数：7
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