FE(OTEF5)3, PREPARATION, STRUCTURE, AND REACTIVITY

被引：16

作者：

DREWS, T ^{[1
]}

SEPPELT, K ^{[1
]}

机构：

[1] FREE UNIV BERLIN,INST ANORGAN & ANALYT CHEM,FABECKSTR 35-35,W-1000 BERLIN 45,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 606卷 / 15期

关键词：

IRON TRIS(PENTAFLUOROOXOTELLURATE(VI)); TRIGONAL PLANAR IRON; PREPARATION; CRYSTAL STRUCTURE; NONACHLORIDITELLURATE (IV);

D O I：

10.1002/zaac.19916060120

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

FeCl3 reacts with ClOTeF5 under formation of Fe(OTeF5)3. From SO2ClF solutions an adduct Fe(OTeF5)3 . 3SO2ClF can be crystallized. This has a distorted octahedral iron oxygen co-ordination. The solvate-free compound is trigonal-planar, according to its Mossbauer spectrum. It has an extreme reactivity towards bases. Only alkanes and perfluoro-alkanes remain unaffected. Attempts to coordinate P(OC2H5)3 in SO2ClF solution result in a complex reaction under formation of [P(OC2H5)4]+ [Te2Cl9]- and iron fluoride(s).

引用

页码：201 / 207

页数：7

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