PALLADIUM COMPLEXES WITH THE TRIDENTATE DIANIONIC LIGAND PYRIDINE-2,6-BIS(THIOCARBOXYLATE), PDTC - CRYSTAL-STRUCTURE OF (N-BU4N)[PD(PDTC)BR]

被引：25

作者：

ESPINET, P ^{[1
]}

LORENZO, C ^{[1
]}

MIGUEL, JA ^{[1
]}

BOIS, C ^{[1
]}

JEANNIN, Y ^{[1
]}

机构：

[1] UNIV PARIS 06,CHIM MET TRANSIT LAB,CNRS,UA 419,F-75252 PARIS 05,FRANCE

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 09期

关键词：

D O I：

10.1021/ic00087a050

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Pd(acac)2] with pyridine-2,6-bis-(thiocarboxylic) acid (H-2pdtc) in chloroform affords [Pd(pdtc)]2, which has been used as starting material in the preparation of a variety of neutral and anionic complexes [Pd(pdtc)L]0,- containing the planar tridentate ligand pdtc. The X-ray structure of (n-Bu4N)[Pd(pdtc)Br] shows the pdtc dianion as a S,N,S-tridentate chelate ligand forming two strain-free palladacycles.

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页码：2052 / 2055

页数：4

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