2-Amino-5-nitropyridinium hydrogen oxalate

被引：7

作者：

Rajkumar, M. Ambrose ^{[1
]}

Xavier, S. Stanly John ^{[2
]}

Anbarasu, S. ^{[1
]}

Devarajan, Prem Anand ^{[1
]}

NizamMohideen, M. ^{[3
]}

机构：

[1] St Xaviers Coll Autonomous, Dept Phys, Phys Res Ctr, Palayankottai 627002, Tamil Nadu, India

[2] St Xaviers Coll Autonomous, Dept Chem, Palayankottai 627002, Tamil Nadu, India

[3] New Coll Autonomous Chennai, Dept Phys, Chennai 600014, Tamil Nadu, India

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

关键词：

single-crystal X-ray study; T= 293 K; mean sigma(C-C) = 0.002 A(degrees); R factor = 0.039; wR factor = 0.110; data-to-parameter ratio = 10.6;

D O I：

10.1107/S160053681400525X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the cation of the title molecular salt, C5H6N 3O2 +·C2HO4 -, the dihedral angle between the aromatic ring and the nitro group is 3.5(3)°; in the anion, the dihedral angle between the CO2 and CO2H planes is 10.5(2)°. In the crystal, the anions are linked into [100] chains by O-H..O hydrogen bonds. The cations cross-link the chains by way of N-H..O hydrogen bonds and the structure is consolidated by C-H..O interactions.

引用

页码：O473 / +

页数：8

共 17 条

[1] Redetermination of para-aminopyridine (fampridine, EL-970) at 150 K [J].

Anderson, FP ;

Gallagher, JF ;

Kenny, PTM ;

Lough, AJ .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 :O1350-O1353

[2] 2-Amino-6-methylpyridinium 2,2,2-trichloroacetate [J].

Babu, K. Syed Suresh ;

Peramaiyan, G. ;

NizamMohideen, M. ;

Mohan, R. .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 :O391-+

[3] PATTERNS IN HYDROGEN BONDING - FUNCTIONALITY AND GRAPH SET ANALYSIS IN CRYSTALS [J].

BERNSTEIN, J ;

DAVIS, RE ;

SHIMONI, L ;

CHANG, NL .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (15) :1555-1573

[4]

*BRUK AXS INC, 2004, APEX2 SAINT XPREP

[5] REFINEMENT OF CRYSTAL-STRUCTURES OF ANHYDROUS ALPHA AND BETA-OXALIC ACIDS [J].

DERISSEN, JL ;

SMIT, PH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1974, 30 (SEP15) :2240-2242

[6] WinGX and ORTEP for Windows: an update [J].

Farrugia, Louis J. .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2012, 45 :849-854

[7] Diisopropylammonium Chloride: A Ferroelectric Organic Salt with a High Phase Transition Temperature and Practical Utilization Level of Spontaneous Polarization [J].

Fu, Da-Wei ;

Zhang, Wen ;

Cai, Hong-Ling ;

Ge, Jia-Zhen ;

Zhang, Yi ;

Xiong, Ren-Gen .

ADVANCED MATERIALS, 2011, 23 (47) :5658-+

[8] 5-Acetyl-4-(3-hydroxyphenyl)-6-methyl-1,2,3,4-tetrahydropyrimidin-2-one-tris-(hydroxymethyl)ammonium chloride (2/1) [J].

Huq, C. A. M. A. ;

Fouzia, S. ;

NizamMohideen, M. .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 :O1766-+

[9] Unique assemblies of alternating positively and negatively charged layers, directed by hydrogen bonds, ionic interactions, and π-stacking in the crystal structures of complexes between mellitic acid (benzenehexacarboxylic acid) and five planar aromatic bases [J].

Karle, I ;

Gilardi, RD ;

Rao, CC ;

Muraleedharan, KM ;

Ranganthan, S .

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2003, 33 (10) :727-749

[10] Mercury CSD 2.0 -: new features for the visualization and investigation of crystal structures [J].

Macrae, Clare F. ;

Bruno, Ian J. ;

Chisholm, James A. ;

Edgington, Paul R. ;

McCabe, Patrick ;

Pidcock, Elna ;

Rodriguez-Monge, Lucia ;

Taylor, Robin ;

van de Streek, Jacco ;

Wood, Peter A. .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2008, 41 :466-470

← 1 2 →