ISOTHERMAL VAPOR-LIQUID-EQUILIBRIA FOR THE ETHANOL + 1-PROPANOL + ACETONITRILE + BENZENE SYSTEM

被引：9

作者：

NAGATA, I

机构：

[1] Department of Chemical Engineering, Division of Physical Sciences, Kanazawa University, Kodatsuno 2, Kanazawa

来源：

PHYSICS AND CHEMISTRY OF LIQUIDS | 1990年 / 21卷 / 02期

关键词：

Associated solution; molecular complexation; quaternary vapour liquid equilibria;

D O I：

10.1080/00319109008028475

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Isothermal quaternary vapour-liquid equilibria for mixtures containing ethanol, 1-propanol, acetonitrile and benzene have been measured using a vapour-recirculating Boublik still at 318.15 K. The experimental results compare well with those calculated from the UNIQUAC associated-solution model, which assumes the association of alsochols and the solvation of unlike molecules and includes binary parameters alone. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：137 / 145

页数：9

共 18 条

[1]

[Anonymous], 1980, COMPUTER CALCULATION

[2]

Boublik T., 1984, VAPOUR PRESSURES PUR

[3] A CONTINUOUS LINEAR ASSOCIATION MODEL FOR DETERMINING THE ENTHALPY OF HYDROGEN-BOND FORMATION AND THE EQUILIBRIUM ASSOCIATION CONSTANT FOR PURE HYDROGEN-BONDED LIQUIDS [J].

BRANDANI, V .

FLUID PHASE EQUILIBRIA, 1983, 12 (1-2) :87-104

[4] LIQUID-VAPOUR EQUILIBRIA .5. THE SYSTEM CARBON TETRACHLORIDE+ACETONITRILE AT 45-DEGREES-C [J].

BROWN, I ;

SMITH, F .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1954, 7 (03) :269-272

[5]

Gmehling J., 1982, CHEM DATA SERIES, V1, P197

[6]

Gmehling J., 1980, VAPOR LIQUID EQUILIB, V1

[7] GENERALIZED METHOD FOR PREDICTING 2ND VIRIAL-COEFFICIENTS [J].

HAYDEN, JG ;

OCONNELL, JP .

INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1975, 14 (03) :209-216

[8] THERMODYNAMICS OF ALCOHOL-SOLUTIONS - PHASE-EQUILIBRIA OF BINARY AND TERNARY MIXTURES CONTAINING 2 ALCOHOLS [J].

NAGATA, I ;

OHTSUBO, K .

THERMOCHIMICA ACTA, 1986, 102 :185-205

[9] THERMODYNAMICS OF ALCOHOL-SOLUTIONS - EXCESS MOLAR ENTHALPIES OF BINARY AND TERNARY MIXTURES CONTAINING 2 ALCOHOLS [J].

NAGATA, I ;

GOTOH, K .

THERMOCHIMICA ACTA, 1986, 102 :207-222

[10] ISOTHERMAL VAPOR LIQUID EQUILIBRIUM OF TERNARY MIXTURES FORMED BY 1-PROPANOL, ACETONITRILE AND BENZENE [J].

NAGATA, I .

FLUID PHASE EQUILIBRIA, 1985, 24 (03) :279-287

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