REACTION OF H+ WITH TETRAPHENYLBORATES - AN EXAMPLE OF AN EC MECHANISM AT LIQUID/LIQUID INTERFACES

被引：12

作者：

KONTTURI, AK ^{[1
]}

KONTTURI, K ^{[1
]}

MURTOMAKI, L ^{[1
]}

SCHIFFRIN, DJ ^{[1
]}

机构：

[1] UNIV LIVERPOOL,DEPT CHEM,LIVERPOOL L69 3BX,MERSEYSIDE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1995年 / 91卷 / 19期

关键词：

D O I：

10.1039/ft9959103433

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of H+ ions electrochemically transferred from an aqueous to an organic immiscible phase, with tetraphenylborate and tetrakis(4-chlorophenyl)borate has been studied by cyclic voltammetry and potential-step measurements. The theory of these EC reactions is presented, and it is shown that the rate constant of the chemical step following charge transfer can be easily estimated from the sweep-rate dependence of the voltammograms, by analysing the conditions for which a minimum in the reverse sweep is not observed.

引用

页码：3433 / 3439

页数：7

共 14 条

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[9] USE OF CONVOLUTION VOLTAMMETRY FOR THE DETERMINATION OF SINGLE-ION GIBBS ENERGIES OF TRANSFER
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