CONVERSION OF ATMOSPHERIC DIOXYGEN TO A MU-ETA(2),ETA(2)-PEROXO BRIDGE IN A DINUCLEAR URANIUM(VI) COMPLEX

被引：31

作者：

DOYLE, GA

GOODGAME, DML

SINDEN, A

WILLIAMS, DJ

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 14期

关键词：

D O I：

10.1039/c39930001170

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N,N'-Ethylenebis(2-pyrrolidone) (ebpyrr) reacts with uranyl nitrate in acetonitrile, methanol, or nitromethane to form a helical chain Polymer [UO2(NO3)2(ebpyrr)]n and, on exposure to air, also a dinuclear mu-eta2,eta2-peroxo-bridged complex {[(UO2)(NO3)(ebpyrr)]2(mu-O2)}.

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页码：1170 / 1172

页数：3

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