STRUCTURAL CHARACTERIZATION OF INFINITE 3-DIMENSIONAL [CD4(CN)9]-ION

被引：25

作者：

KITAZAWA, T

SUGISAWA, H

TAKEDA, M

IWAMOTO, T

机构：

[1] JEOL LTD,DIV ANALYT INSTRUMENTS,CTR APPLICAT & RES,NMR APP LABO,TOKYO 196,JAPAN

[2] UNIV TOKYO,COLL ARTS & SCI,DEPT CHEM,TOKYO 153,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 24期

关键词：

D O I：

10.1039/c39930001855

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single crystal X-ray determination reveals the first example of a mineralomimetic [Cd4(CN)9]- open framework consisting of interconnected tetrahedral and octahedral cadmium centres in the ratio 3:1, while solid state Cd-113 NMR spectroscopy indicates that some of the bridged cyano groups between the Cd atoms are disordered.

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页码：1855 / 1856

页数：2

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